Perloffite

BaMn2+2Fe3+2(PO4)3(OH)3
IMA status
  • Approved
IMA symbol
Plf
Discovered
1977
Also known as
  • IMA1976-002
  • Perloffiet

Where it forms, where it's found

Geological setting

Pegmatite

Type locality
Big Chief Mine
  1. Glendale
  2. Keystone Mining District
  3. Pennington County
  4. South Dakota
  5. USA

43.8650°, -103.3819°

10recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Brownish black · green-brown · black
Streak
Greenish yellow
Cleavage
Perfect

on (100)

Density
4.00 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70 – 80° · 2V calc = 70°
Refractive index
1.793 – 1.808
Surface relief
Very high
Principal indices
nα 1.793 · nβ 1.803 · nγ 1.808
Pleochroism
Visible

X=Z= dark greenish brown Y= light greenish brown

Dispersion
r << v
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 9.22 Å · b = 12.42 Å · c = 4.99 Å
Cell angles
β = 100.39 °
Ratio a:b:c
1 : 1.347 : 0.541
Z
2
Morphology

Crystals resemble spearheads, parallel and radial growths common. May be massive. Type material shows (001), (101), (021), (131).

Twinning

None observed

Type-locality form

Lustrous, black, spear-shaped crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
34.54%
56BaBariumBarium1137.327137.327
19.76%
26FeIronIron255.845111.690
16.08%
25MnManganeseManganese254.938109.876
15.81%
15PPhosphorusPhosphorus330.97492.922
13.37%
1HHydrogenHydrogen31.0083.024
0.44%
Total694.824100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1976-002
  • Perloffiet

In other languages

French
Perloffite
German
Perloffit
Italian
perloffite

Classification

Strunz
10th ed.

8.BH.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.20PerloffiteSpecies
Dana
8th ed.

41.09.01.04

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.09(AB)5(XO4)3ZqType
  • 41.09.01Kulanite GroupGroup
  • 41.09.01.04PerloffiteSpecies
CIM

19.5.15

  • 19PhosphatesClass
  • 19.5Phosphates of Sr and BaGroup
  • 19.5.15PerloffiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1977Fleischer, Michael, Pabst, Adolf, Mandarino, J. A., Chao, George Y. (1977) New mineral names. American Mineralogist, 62 (9-10) 1057-1061
  2. 1977Kampf, Anthony R. (1977) A New Mineral: Perloffite, the Fe3+ Analogue of Bjarebyite. The Mineralogical Record, 8 (2) 112-114
  3. 1988Birch, W.D., Mumme, W.G. (1988) Hentschelite and Perloffite from the Spring Creek Copper Mine, South Australia. Mineralogical Magazine, 52 (366) 408-411 doi:10.1180/minmag.1988.052.366.16DOI: 10.1180/minmag.1988.052.366.16
  4. 2005(2005) Perloffite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2011Elliott, P., Willis, A. C. (2011) The crystal structure of perloffite. Mineralogical Magazine, 75 (2) 317-325 doi:10.1180/minmag.2011.075.2.317DOI: 10.1180/minmag.2011.075.2.317
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Perloffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/perloffite-3164},
  note      = {Accessed 2026-05-11}
}