Where it forms, where it's found
- Geological setting
Pegmatite
- Type locality
- Big Chief Mine
- Glendale
- Keystone Mining District
- Pennington County
- South Dakota
- USA
43.8650°, -103.3819°
Physical
Optical
- Optical type
- Biaxial (-) · 2V measured = 70 – 80° · 2V calc = 70°
- Refractive index
- 1.793 – 1.808
- Surface relief
- Very high
- Principal indices
- nα 1.793 · nβ 1.803 · nγ 1.808
- Pleochroism
- Visible
X=Z= dark greenish brown Y= light greenish brown
- Dispersion
- r << v
Crystallography
- Space group
- P21/m
- Cell parameters
- a = 9.22 Å · b = 12.42 Å · c = 4.99 Å
- Cell angles
- β = 100.39 °
- Ratio a:b:c
- 1 : 1.347 : 0.541
- Z
- 2
- Morphology
Crystals resemble spearheads, parallel and radial growths common. May be massive. Type material shows (001), (01), (021), (31).
- Twinning
None observed
- Type-locality form
Lustrous, black, spear-shaped crystals.
Chemical composition
Synonyms
- IMA1976-002
- Perloffiet
In other languages
- French
- Perloffite
- German
- Perloffit
- Italian
- perloffite
Classification
8.BH.20
- 8Phosphates, Arsenates, VanadatesClass
- 8.BPhosphates, etc., with additional anions, without H2ODivision
- 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
- 8.BH.20PerloffiteSpecies
41.09.01.04
- 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
- 41.09(AB)5(XO4)3ZqType
- 41.09.01Kulanite GroupGroup
- 41.09.01.04PerloffiteSpecies
19.5.15
- 19PhosphatesClass
- 19.5Phosphates of Sr and BaGroup
- 19.5.15PerloffiteSpecies
Group, growth & confusion
BjarebyiteBaMn2+2Al2(PO4)3(OH)3Mineral—- JohntomaiteBaFe2+2Fe3+2(PO4)3(OH)3Mineral—
KulaniteBaFe2+2Al2(PO4)3(OH)3Mineral—- Nigelcookite PbFe2+2V3+2(PO4)3(OH)3Mineral—
- PenikisiteBaMg2Al2(PO4)3(OH)3Mineral—
- Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3Mineral—
PlumboperloffitePbMn2+2Fe3+2(PO4)3(OH)3Mineral—- StrontioperloffiteSrMn2+2Fe3+2(PO4)3(OH)3Mineral—
Literature, links & citation
- 1977Fleischer, Michael, Pabst, Adolf, Mandarino, J. A., Chao, George Y. (1977) New mineral names. American Mineralogist, 62 (9-10) 1057-1061
- 1977Kampf, Anthony R. (1977) A New Mineral: Perloffite, the Fe3+ Analogue of Bjarebyite. The Mineralogical Record, 8 (2) 112-114
- 1988Birch, W.D., Mumme, W.G. (1988) Hentschelite and Perloffite from the Spring Creek Copper Mine, South Australia. Mineralogical Magazine, 52 (366) 408-411 doi:10.1180/minmag.1988.052.366.16DOI: 10.1180/minmag.1988.052.366.16
- 2005(2005) Perloffite. Handbook of Mineralogy. Mineralogical Society of America
- 2011Elliott, P., Willis, A. C. (2011) The crystal structure of perloffite. Mineralogical Magazine, 75 (2) 317-325 doi:10.1180/minmag.2011.075.2.317DOI: 10.1180/minmag.2011.075.2.317
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Perloffite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/perloffite-3164},
note = {Accessed 2026-05-11}
}