Penikisite

BaMg2Al2(PO4)3(OH)3
IMA status
  • Approved
IMA symbol
Pks
Discovered
1977
Also known as
  • IMA1976-023
  • Penikisiet

Where it forms, where it's found

Type locality
Rapid Creek
  1. Dawson mining district
  2. Yukon
  3. Canada

68.5400°, -136.7996°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Blue to green
Streak
Very pale green to white
Cleavage
Distinct/Good

Two fair to good cleavages {O10} and (100)

Density
3.79 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 52 – 56° · 2V calc = 54°
Refractive index
1.684 – 1.705
Surface relief
High
Principal indices
nα 1.684 · nβ 1.688 · nγ 1.705
Pleochroism
Visible

X grass-green, Y blue-green, Z pale pink

Dispersion
very strong asymmetrical dispersion with dispersion of the optic axes r>>y.
Extinction
X ~ Y > Z
UV response
Not fluorescent under short-wave and long-wave ultraviolet light
Notes

b~Y and c:Z=-6°, although b:Y ranges from 0° to 19°

Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 8.9577(4) Å · b = 12.0150(5) Å · c = 4.9070(2) Å
Cell angles
β = 100.505(2) °
Ratio a:b:c
1 : 1.341 : 0.548
Unit cell volume
519.37 ų
Z
2
Type-locality form

The same as kulanite. Well formed blue to green crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
41.68%
56BaBariumBarium1137.327137.327
23.85%
15PPhosphorusPhosphorus330.97492.922
16.14%
13AlAluminiumAluminium226.98253.964
9.37%
12MgMagnesiumMagnesium224.30548.610
8.44%
1HHydrogenHydrogen31.0083.024
0.52%
Total575.832100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1976-023
  • Penikisiet

In other languages

French
Penikisite
German
Penikisit
Spanish
Penikisita
Italian
Penikisite

Classification

Strunz
10th ed.

8.BH.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.20PenikisiteSpecies
Dana
8th ed.

41.09.01.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.09(AB)5(XO4)3ZqType
  • 41.09.01Kulanite GroupGroup
  • 41.09.01.02PenikisiteSpecies
CIM

19.5.11

  • 19PhosphatesClass
  • 19.5Phosphates of Sr and BaGroup
  • 19.5.11PenikisiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1977Mandarino, J. A., Sturman, B. D., Corlett, M. I. (1977) Penikisite, the magnesium analogue of kulanite, from the Yukon Territory, Canada. The Canadian Mineralogist, 15 (3) 393-395
  2. 1992Robinson, George W., Van Velthuizen, Jerry, Ansell, H. Gary, Sturman, B. Darko (1992) Mineralogy of the Rapid Creek and Big Fish River Area, Yukon Territory. The Mineralogical Record, 23 (4) 1-47
  3. 2005(2005) Penikisite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2013Bowman, Michael G., Downs, Robert T., Yang, Hexiong (2013) Penikisite, BaMg2Al2(PO4)3(OH)3, isostructural with bjarebyite. Acta Crystallographica Section E Structure Reports Online, 69 (2) 4-5 doi:10.1107/s1600536812051793DOI: 10.1107/s1600536812051793
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Penikisite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/penikisite-3148},
  note      = {Accessed 2026-05-11}
}