Phosgenite

Pb2(CO3)Cl2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pho
Discovered
1800
Also known as
  • Bleihornerz
  • Bleikerat
  • Chlorbleispath
  • +18 more

Where it forms, where it's found

Geological setting

Surface conditions in lead-bearing ore bodies.

Type locality
Cromford
  1. Derbyshire Dales District
  2. Derbyshire
  3. England
  4. UK
158recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Transparent · Translucent
Colour
Colourless · white · yellow · brown · greenish or pink · colourless in transmitted light.
Streak
White
Tenacity
sectile
Cleavage
Distinct/Good

Distinct on (001) and (110); less distinct on (010)

The crystals can easily be flexed about directions perpendicular to [001].

Fracture
Conchoidal
Density
6.12 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.118 – 2.145
Surface relief
Very high
Principal indices
nω 2.118 · nε 2.145
Pleochroism
Weak

Very weakly pleochroic with O - reddish and E - greenish in thick sections.

UV response
Fluoresces yellow in LW & SW UV, X-rays and cathode rays.
Notes

Weakly biaxial at times, noticeable after mechanical deformation.

Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#179
Cell parameters
a = 8.16 Å · c = 8.883(6) Å
Z
4
Morphology

Crystals short prismatic to prismatic [001]; thick tabular rare (001); thin tabular very rare. Normally terminated by large (001), with (111) dominant at times. Massive, granular.

Translation gliding
Translation gliding with T(110), t[001].
Epitaxy

Cerussite on phosgenite, with cerussite (100) [010] parallel to phosgenite (001)[120].

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
76.00%
17ClChlorineChlorine235.45070.900
13.00%
8OOxygenOxygen315.99947.997
8.80%
6CCarbonCarbon112.01112.011
2.20%
Total545.308100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bleihornerz
  • Bleikerat
  • Chlorbleispath
  • Chromfordit
  • Corneous Lead
  • Corneous Lead Ore
  • Cromfordit
  • Cromfordite
  • Galenoceratit
  • Galenoceratita
  • Galenoceratite
  • Horn lead
  • Hornblei
  • Lead Chlorocarbonate
  • Lead murio-carbonate
  • Matlockite (of Chapman)
  • Phosgen-spath
  • Phosgeniet
  • Plomb carbonaté muriatifère
  • Plomb chloro-carbonaté
  • Plomb corné

In other languages

French
Cromfordite · Galenoceratite · Hornblei · Kérasine · Murio-carbonate de plomb · Phosgénite · Plomb carbonaté muriatifère · Plomb chloro-carbonaté · Plomb corné
German
Bleihornerz · Hornblei · Kerasin · Phosgenit
Spanish
Fosgenita
Italian
Fosgenite
Russian
Керазин · Роговая свинцовая руда · Роговой свинец · Фосгенит

Classification

Strunz
10th ed.

5.BE.20

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BEWith Pb, BiGroup
  • 5.BE.20PhosgeniteSpecies
Dana
8th ed.

16a.03.04.01

  • 16aAnhydrous Carbonates Containing Hydroxyl or HalogenClass
  • 16a.03(AB)2(XO3)ZqType
  • 16a.03.04— unnamed intermediate level —Group
  • 16a.03.04.01PhosgeniteSpecies
CIM

12.1.23

  • 12Carbonates with other anionsClass
  • 12.1Carbonates with halidesGroup
  • 12.1.23PhosgeniteSpecies

Group, growth & confusion

Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 78 (as "Hornblei").
  2. 1802Klaproth, M. H. (1802) LXXXVI. Untersuchung des salzsauren Bleierzes. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.141-145.
  3. 1804Jameson, Robert (1804) System of Mineralogy (1st ed.) Robert Jameson, Edinburgh.
  4. 1832Breithaupt, A. (1832) Vollständige Characteristik etc., 2nd. Ed.: 61 (as Phosgen-spath).
  5. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosgenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosgenite-3195},
  note      = {Accessed 2026-05-11}
}