Phosphoinnelite

Na3Ba4Ti3Si4O14(PO4)2O2F
IMA status
  • Approved
IMA symbol
Pinn
IMA approved
2005
Also known as
  • IMA2005-022
  • Phosphoinneliet

Where it forms, where it's found

Geological setting

Agpaitic pegmatite veins cross-cutting calcite carbonatite in a phlogopite deposit

Type locality
Kovdor Phlogopite mine
  1. Kovdor Massif
  2. Kovdorsky District
  3. Murmansk Oblast
  4. Russia

67.5892°, 30.4592°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Yellow–brown · honey · occasionally brown.
Streak
pale yellow
Tenacity
brittle
Cleavage
Perfect

on (010), good on (100)

Fracture
Step-Like
Density
3.82 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 90° · 2V calc = 84°
Refractive index
1.73 – 1.764
Surface relief
High
Principal indices
nα 1.730 · nβ 1.745 · nγ 1.764
Michel-Lévy diagramhighlighted lineδ = 0.0340
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]340 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 5.38(2) Å · b = 7.10(2) Å · c = 14.76(5) Å
Cell angles
α = 99.00(7) ° · β = 94.94(6) ° · γ = 90.14(8) °
Ratio a:b:c
1 : 1.320 : 2.743
Unit cell volume
555 ų
Z
1
Type-locality form

Lath-like crystals up to 0.2 x 1 x 6 mm in sheaf- and rosette-like aggregates

Comment

Point Group: _1 or 1; Space Group: P_1 or P1.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium4137.327549.308
41.02%
8OOxygenOxygen2415.999383.976
28.67%
22TiTitaniumTitanium347.867143.601
10.72%
14SiSiliconSilicon428.085112.340
8.39%
11NaSodiumSodium322.99068.970
5.15%
15PPhosphorusPhosphorus230.97461.948
4.63%
9FFluorineFluorine118.99818.998
1.42%
Total1339.141100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-022
  • Phosphoinneliet

In other languages

German
IMA 2005-022 · Phosphoinnelit
Italian
phosphoinnelite

Classification

Strunz
10th ed.

9.BE.40

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.40PhosphoinneliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2006I. V. Pekov, N. V. Chukanov, I. M. Kulikova, D. L. Belakovsky (2006): Phosphoinnelite, Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3, a new mineral from agpaitic pegmatites of Kovdor massif, Kola Peninsula. Proceedings of the Russian Mineralogical Society: 135(3): 52-60.
  2. 2011(2011) Phosphoinnelite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphoinnelite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphoinnelite-27577},
  note      = {Accessed 2026-05-11}
}