Polyphite

Na6(Na4Ca2)2Na2Ti2Na2Ti2(Si2O7)2(PO4)6O4F4
IMA status
  • Approved
IMA symbol
Ppt
Discovered
1992
Also known as
  • Polyphiet
  • Polyphita

Where it forms, where it's found

Geological setting

Alkalic pegmatite.

Type locality
Alluaiv Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8645°, 34.5124°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Light-brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect (001) and less perfect (110) and (100).

Fracture
Step-Like
Density
3.07 g/cm³

Optical

Optical type
· 2V measured = 56°
Refractive index
1.6 – 1.676
Surface relief
Moderate
Principal indices
nα 1.600 · nβ 1.658 · nγ 1.676
Pleochroism
Visible

Colorless (X) to yellowish (Y, Z) with X < Y ~ Z.

UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0760
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]760 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation760 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 5.3933(2) Å · b = 7.0553(3) Å · c = 26.451(1) Å
Cell angles
α = 95.216(1) ° · β = 93.49(1) ° · γ = 90.101(1) °
Ratio a:b:c
1 : 1.308 : 4.904
Unit cell volume
1000.44 ų
Z
2
Type-locality form

Flakes on (001), 1-2 mm thick and 3 mm across, grown epitaxially on lomonosovite and soboloveite.

Comment

Cell parameters from Sokolova et al. (2005).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4215.999671.958
37.09%
11NaSodiumSodium1822.990413.820
22.84%
22TiTitaniumTitanium447.867191.468
10.57%
15PPhosphorusPhosphorus630.974185.844
10.26%
20CaCalciumCalcium440.078160.312
8.85%
14SiSiliconSilicon428.085112.340
6.20%
9FFluorineFluorine418.99875.992
4.19%
Total1811.734100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sr
  • Ba
  • Fe
  • Zr
  • Nb

Synonyms

  • Polyphiet
  • Polyphita

In other languages

German
IMA 1990-025 · Polyphit
Italian
Polifite · Polyphite · Polyphite-VII · Polyphite-VIII

Classification

Strunz
10th ed.

9.BE.47

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.47PolyphiteSpecies
Dana
8th ed.

56.04.01.02

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.04Si2O7 Groups and O, OH, F, and H2O with [Si2O7] with other cation groupsType
  • 56.04.01Lomonosovite groupGroup
  • 56.04.01.02PolyphiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1987Doklady Akademiia Nauk, SSSR (USSR)(1987): 294: 357.
  2. 1987Mineralogicheskiy Zhurnal (1987): 9(3): 28.
  3. 1987Sokolova, E.V., Egorov-Tismenko, Y.K., Khomyakov, A.P. (1987) Crystal structure of Na17Ca3Mg(Ti,Mn)4[Si2O7]2[PO4]6O2F6, a new representative of the family of layered titanium silicates. Soviet Physics - Doklady, 32, 344-347.
  4. 1992Khomyakov, A.P., Nechelyustov, G.N., Sokolova, E.A., Dorokhova, G.I. (1992) Quadruphite Na14CaMgTi4-[Si207]2[P04]404F2 and polyphite Na17Ca3Mg(Ti,Mn)4-[Si207]2[P04]602F6: New minerals of the lomonosovite group. Zapiski Vserossiskogo Mineralogicheskogo Obshchetstva, 121(1), 105-112 (in Russian).
  5. 1993Jambor, John L., Vanko, David A. (1993) New Mineral Names. American Mineralogist, 78 (11-12) 1314-1319
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polyphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polyphite-3262},
  note      = {Accessed 2026-05-11}
}