Pyrophanite

Mn2+TiO3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pph
Discovered
1890
Also known as
  • Pyrophaniet

Where it forms, where it's found

Geological setting

Metamorphosed manganese deposits.

Type locality
Harstigen Mine
  1. Pajsberg
  2. Persberg ore district
  3. Filipstad
  4. Värmland County
  5. Sweden

59.7853°, 14.3139°

280recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Blood red · greenish yellow · brownish · blackish

Orange in transmitted light. Greenish yellow colour tentatively attributed to Ce content (Lee, 1955).

Streak
Ochre yellow with greenish tinge
Cleavage
Perfect

On (0221) perfect; (1012) less perfect.

Fracture
Conchoidal · Sub-Conchoidal
Density
4.537 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.21 – 2.481
Surface relief
Very high
Principal indices
nω 2.481 · nε 2.21
Tropism
Anisotropic
Reflectance R%
(23.5,19.9) 400, (22.7,19.6) 420, (21.8,18.9) 440, (21.1,18.2) 460, (20.4,17.6) 480, (19.9,17.1) 500, (19.4,16.7) 520, (19.0,16.3) 540, (18.8,16.1) 560, (18.5,15.9) 580, (18.3,15.7) 600, (18.2,15.6) 620, (18.0,15.5) 640, (17.8,15.4) 660, (17.8,15.3) 680, (17.6,15.2) 700
Reflected-light panel
19.6 %anisotropic · dual curve
Specimen sRGB 158, 112, 65
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 5.13948(7) Å · c = 14.2829(4) Å
Z
6
Morphology

Fine scaly; tabular.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese154.93854.938
36.43%
8OOxygenOxygen315.99947.997
31.83%
22TiTitaniumTitanium147.86747.867
31.74%
Total150.802100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Zn

Synonyms

  • Pyrophaniet

In other languages

French
pyrophanite
German
Pyrophanit
Spanish
Pirofanita
Italian
Pirofanite

Classification

Strunz
10th ed.

4.CB.05

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.05PyrophaniteSpecies
Dana
8th ed.

04.03.05.03

  • 04Simple OxidesClass
  • 04.03A2X3Type
  • 04.03.05Ilmenite GroupGroup
  • 04.03.05.03PyrophaniteSpecies
CIM

7.9.13

  • 7Oxides and HydroxidesClass
  • 7.9Oxides of TiGroup
  • 7.9.13PyrophaniteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  2. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  3. 1955Lee, Donald E. (1955) Occurrence of pyrophanite in Japan. American Mineralogist, 40 (1-2) 32-40
  4. 1969Welin, E. (1969) Notes on the mineralogy of Sweden 6. X-ray powder data for minerals from Långban and the related mineral deposits of Central Sweden. Arkiv för Mineralogi och Geologi, 4 (6, nr 30). 499-541
  5. 1985Craig, J.R., Sandhaus, D.J., Guy, R.E. (1985) Pyrophanite MnTiO3 from Sterling Hill, New Jersey. The Canadian Mineralogist, 23, 491-494.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pyrophanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pyrophanite-3322},
  note      = {Accessed 2026-05-11}
}