Pennantite

Mn2+5Al(Si3Al)O10(OH)8
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pnn
Discovered
1946
Also known as
  • Grovesite

Where it forms, where it's found

Geological setting

Hydrothermal alteration of manganese deposits.

Hydrothermal alteration of manganese minerals

Type locality
Benallt Mine
  1. Rhiw
  2. Aberdaron
  3. Gwynedd
  4. Wales
  5. UK

52.8207°, -4.6390°

30recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Orange-red · red-brown · brown · dark red · dark green · black
Tenacity
flexible
Cleavage
Perfect

on (001)

Fracture
Micaceous
Density
2.89 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.615 – 1.673
Surface relief
Moderate
Principal indices
nα 1.615 – 1.664 · nβ 1.661 · nγ 1.622 – 1.673
Birefringence
0.015
Pleochroism
Visible

X = pinkish orange, orange-buff, reddish brown Y = Z = orange, yellowish orange, very dark brown

Dispersion
weak
UV response
Not fluorescent in ultraviolet light
Notes

Absorption: Y = Z > X.

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 5.45 Å · b = 9.50 Å · c = 14.40 Å
Cell angles
α = 90 ° · β = 97.3 ° · γ = 90 °
Ratio a:b:c
1 : 1.743 : 2.642
Z
2
Morphology

Lamellar crystals and flakes.

Type-locality form

Very poorly crystallized as patches and small specks in the matrix. Less commonly it occurs as minute flakes in the ore and sometimes as a constituent of very thin veins which traverse the ore. In some specimens the mineral is better developed forming orange-brown micaceous flakes to 0.5 mm. Patches of the mineral in the matrix frequently enclose very small garnets.

Comment

Point Group: _1 or 1; Space Group: P_1 or P1.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
40.62%
25MnManganeseManganese554.938274.690
38.75%
14SiSiliconSilicon328.08584.255
11.88%
13AlAluminiumAluminium226.98253.964
7.61%
1HHydrogenHydrogen81.0088.064
1.14%
Total708.955100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Zn
  • Mg
  • Ba
  • H2O

Synonyms

  • Grovesite

In other languages

French
Pennantite
German
Pennantit
Italian
Pennantite

Classification

Strunz
10th ed.

9.EC.55

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.55PennantiteSpecies
Dana
8th ed.

71.04.01.08

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.04Sheets of 6-membered rings interlayered 1:1, 2:1, and octahedraType
  • 71.04.01Chlorite group (Tri-Dioctahedral)Group
  • 71.04.01.08PennantiteSpecies
CIM

16.16.7

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.16Aluminosilicates of MnGroup
  • 16.16.7PennantiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1946Campbell Smith, W., Bannister, F. A., Hey, Max H. (1946) Pennantite, a new manganese-rich chlorite from Benallt mine, Rhiw, Carnarvonshire. Mineralogical Magazine and Journal of the Mineralogical Society, 27 (194) 217-220 doi:10.1180/minmag.1946.027.194.01 DOI: 10.1180/minmag.1946.027.194.01
  2. 1947Fleischer, M. (1947) New mineral names. American Mineralogist, 32 (3-4). 254-255
  3. 1965Kayupova, M.M. (1965) Pennantite from Ushkatyn Deposit in Central Kazakhstan. Doklady Akademii Nauk SSSR, 163(1), 189.
  4. 1983Bayliss, P. (1983). Polytypes of pennantite. Canadian Mineralogist, 21(3), 545-547.
  5. 1989Abrecht, Jürgen (1989) Manganiferous phyllosilicate assemblages: occurrences, compositions and phase relations in metamorphosed Mn deposits. Contributions to Mineralogy and Petrology, 103 (2). 228-241 doi:10.1007/bf00378509DOI: 10.1007/bf00378509
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pennantite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pennantite-3150},
  note      = {Accessed 2026-05-11}
}