Thermonatrite

Na2(CO3) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tnat
Discovered
1845
Also known as
  • Natürliches mineralisches Alkali
  • Prismatisches Natronsalz
  • Soude carbonatée prismatique
  • +3 more

Where it forms, where it's found

Geological setting

As efflorescences on soil in arid regions and in saline lakes.

59recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 1.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless to grey or yellow · white
Streak
White
Tenacity
sectile
Cleavage
Poor/Indistinct

On (100), difficult.

Density
2.255 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 48° · 2V calc = 46°
Refractive index
1.42 – 1.524
Surface relief
Low
Principal indices
nα 1.42 · nβ 1.506 · nγ 1.524
Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.1040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1040 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1040 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#68
Cell parameters
a = 10.72 Å · b = 5.24 Å · c = 6.46 Å
Ratio a:b:c
1 : 0.489 : 0.603
Morphology

Forms crusts and efflorescence. Crystals thin-lamellar (001), also tabular (010); elongated [100] (artificial material).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
51.61%
11NaSodiumSodium222.99045.980
37.08%
6CCarbonCarbon112.01112.011
9.69%
1HHydrogenHydrogen21.0082.016
1.62%
Total124.003100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Natürliches mineralisches Alkali
  • Prismatisches Natronsalz
  • Soude carbonatée prismatique
  • Thermonatriet
  • Thermonatrita
  • Thermonitrit

In other languages

French
Thermonatrite
German
Thermonatrit
Spanish
Termonatrita
Italian
termonatrite
Russian
Термонатрит

Classification

Strunz
10th ed.

5.CB.05

  • 5CarbonatesClass
  • 5.CCarbonates without additional anions, with H2ODivision
  • 5.CBWith large cations (alkali and alkali-earth carbonates)Group
  • 5.CB.05ThermonatriteSpecies
Dana
8th ed.

15.01.01.01

  • 15Hydrated Normal CarbonatesClass
  • 15.01A(XO3)·xH2OType
  • 15.01.01— unnamed intermediate level —Group
  • 15.01.01.01ThermonatriteSpecies
CIM

11.1.5

  • 11CarbonatesClass
  • 11.1Carbonates of the alkali metals and ammoniumGroup
  • 11.1.5ThermonatriteSpecies

Group, growth & confusion

Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1747Wallerius, J.G (1747) Mineralogia, eller Mineralriket. Stockholm (as Natron, Alkali orientale impurum terrestre, Jordblandadt, Alkaliskt-salt).
  2. 1825Mohs-Haidinger (1825): 2: 29 (as Prismatisches Natronsalz).
  3. 1847Hausmann, J.F.L. (1847) Handbuch der Mineralogie 3 volumes, Göttingen. Second edition, vol. 2: 1411 (as Thermonitrit).
  4. 1856Dufrénoy, A. (1856): 2: 220 (as Soude carbonatée prismatique).
  5. 1856Dufrénoy (1856): 2: 220 (as Soude carbonatée prismatique).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Thermonatrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/thermonatrite-3938},
  note      = {Accessed 2026-05-11}
}