Nahcolite

NaH(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nah
Discovered
1928
Also known as
  • Nahcoliet
  • Nahcolit
  • Sodium Bicarbonate
  • +1 more

Where it forms, where it's found

Geological setting

In a lava tunnel.

Precipitate from hot springs; as efflorescences around saline lakes and in brines; formed at a late stage in differentiated alkalic massifs; as tiny daughter crystals in fluid inclusions in a variety of hydrothermally formed mineral species.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
67recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Resinous
Transparency
Transparent
Colour
Colourless · white · greyish · colourless in transmitted light.
Streak
White
Cleavage
Perfect

On (101) perfect; on (111) good; on (100) distinct.

Fracture
Conchoidal
Density
2.21 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75° · 2V calc = 74°
Refractive index
1.375 – 1.583
Surface relief
Low
Principal indices
nα 1.375 · nβ 1.498 – 1.503 · nγ 1.583
Pleochroism
Non-pleochroic

colorless in thin section

Dispersion
r < v weak
Notes

Surface relief is stated here as "low". However, like many carbonates, the actual surface is variable, in this case changing with stage rotation from low positive (γ vibration direction) to very high negative (α vibration direction).

Michel-Lévy diagramhighlighted lineδ = 0.2080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2080 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2080 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.525(4) Å · b = 9.72(4) Å · c = 3.53(3) Å
Cell angles
β = 93.38 °
Ratio a:b:c
1 : 1.292 : 0.469
Z
4
Morphology

Crystals prismatic [001] with (110) and (010) dominant. Normally terminated by (101) and minor (111); also by (111) and (101) in equal development. Porous masses, friable crystal aggregates.

Twinning

Very common, with (101) as the twin and composition plane. Both contact and penetration twins, often as reticulated groups, and flattened (010).

Comment

Space Group: P21/n (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
57.13%
11NaSodiumSodium122.99022.990
27.37%
6CCarbonCarbon112.01112.011
14.30%
1HHydrogenHydrogen11.0081.008
1.20%
Total84.006100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Nahcoliet
  • Nahcolit
  • Sodium Bicarbonate
  • Thermokalite

In other languages

French
Nahcolite
German
Nahcolith
Spanish
Nahcolita
Italian
Nahcolite
Chinese
蘇打石 · 重碳钠盐
Russian
Нахколит
Arabic
ناهكوليت

Classification

Strunz
10th ed.

5.AA.15

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.AAAlkali carbonatesGroup
  • 5.AA.15NahcoliteSpecies
Dana
8th ed.

13.01.01.01

  • 13Acid CarbonatesClass
  • 13.01MiscellaneousType
  • 13.01.01— unnamed intermediate level —Group
  • 13.01.01.01NahcoliteSpecies
CIM

11.1.3

  • 11CarbonatesClass
  • 11.1Carbonates of the alkali metals and ammoniumGroup
  • 11.1.3NahcoliteSpecies

Group, growth & confusion

Often grow together
8 minerals

Literature, links & citation

Citations
  1. https://en.wikipedia.org/wiki/Sodium_bicarbonate
  2. 1845Playfair, L., Joule, J.P. (1845) On atomic volume and specific gravity. Memoirs and Proceedings of the Chemical Society: 2: 401-481.
  3. 1855Schabus, J. (1855) Bestimmung Der Krystallgestalten in Chemischen Laboratorien Erzeugter Producte. Akademie der Wissenschaften, Wien: 294 pgs (97).
  4. 1866Stolba, F. (1866) Ueber die Anwendung gesättigter wässriger Lösungen zur Bestimmung der Dichte der ihnen entsprechenden loslichen Korper (On the use of saturated aqueous solutions to determine the density of the soluble bodies corresponding to them.). Journal für praktische Chemie, Leipzig: 97: 503-510.
  5. 1878Schröder (1878) Ber.: 11: 2018.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nahcolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nahcolite-2831},
  note      = {Accessed 2026-05-11}
}