Where it forms, where it's found
- Geological setting
In a lava tunnel.
Precipitate from hot springs; as efflorescences around saline lakes and in brines; formed at a late stage in differentiated alkalic massifs; as tiny daughter crystals in fluid inclusions in a variety of hydrothermally formed mineral species.
- Type locality
- Mount Vesuvius
- Metropolitan City of Naples
- Campania
- Italy
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Lustre
- Vitreous · Resinous
- Transparency
- Transparent
- Colour
- Colourless · white · greyish · colourless in transmitted light.
- Streak
- White
- Cleavage
- Perfect
On (101) perfect; on (111) good; on (100) distinct.
- Fracture
- Conchoidal
- Density
- 2.21 g/cm³
Optical
- Optical type
- Biaxial (-) · 2V measured = 75° · 2V calc = 74°
- Refractive index
- 1.375 – 1.583
- Principal indices
- nα 1.375 · nβ 1.498 – 1.503 · nγ 1.583
- Pleochroism
- Non-pleochroic
colorless in thin section
- Dispersion
- r < v weak
- Notes
Surface relief is stated here as "low". However, like many carbonates, the actual surface is variable, in this case changing with stage rotation from low positive (γ vibration direction) to very high negative (α vibration direction).
Crystallography
- Cell parameters
- a = 7.525(4) Å · b = 9.72(4) Å · c = 3.53(3) Å
- Cell angles
- β = 93.38 °
- Ratio a:b:c
- 1 : 1.292 : 0.469
- Z
- 4
- Morphology
Crystals prismatic [001] with (110) and (010) dominant. Normally terminated by (101) and minor (111); also by (111) and (11) in equal development. Porous masses, friable crystal aggregates.
- Twinning
Very common, with (101) as the twin and composition plane. Both contact and penetration twins, often as reticulated groups, and flattened (010).
- Comment
Space Group: P21/n (synthetic).
Chemical composition
Synonyms
- Nahcoliet
- Nahcolit
- Sodium Bicarbonate
- Thermokalite
In other languages
- French
- Nahcolite
- German
- Nahcolith
- Spanish
- Nahcolita
- Italian
- Nahcolite
- Chinese
- 蘇打石 · 重碳钠盐
- Russian
- Нахколит
- Arabic
- ناهكوليت
Classification
5.AA.15
- 5CarbonatesClass
- 5.ACarbonates without additional anions, without H2ODivision
- 5.AAAlkali carbonatesGroup
- 5.AA.15NahcoliteSpecies
13.01.01.01
- 13Acid CarbonatesClass
- 13.01MiscellaneousType
- 13.01.01— unnamed intermediate level —Group
- 13.01.01.01NahcoliteSpecies
11.1.3
- 11CarbonatesClass
- 11.1Carbonates of the alkali metals and ammoniumGroup
- 11.1.3NahcoliteSpecies
Group, growth & confusion
Literature, links & citation
- —https://en.wikipedia.org/wiki/Sodium_bicarbonate
- 1845Playfair, L., Joule, J.P. (1845) On atomic volume and specific gravity. Memoirs and Proceedings of the Chemical Society: 2: 401-481.
- 1855Schabus, J. (1855) Bestimmung Der Krystallgestalten in Chemischen Laboratorien Erzeugter Producte. Akademie der Wissenschaften, Wien: 294 pgs (97).
- 1866Stolba, F. (1866) Ueber die Anwendung gesättigter wässriger Lösungen zur Bestimmung der Dichte der ihnen entsprechenden loslichen Korper (On the use of saturated aqueous solutions to determine the density of the soluble bodies corresponding to them.). Journal für praktische Chemie, Leipzig: 97: 503-510.
- 1878Schröder (1878) Ber.: 11: 2018.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Nahcolite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/nahcolite-2831},
note = {Accessed 2026-05-11}
}





