Trona

Na3(HCO3)(CO3) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tn
Discovered
1773
Also known as
  • Ägyptisches Natrium
  • Alkali orientale impurum terrestre
  • Natrum von Tripole
  • +5 more

Where it forms, where it's found

Geological setting

Saline lakes and their evaporites; efflorecences on soils in arid regions.

134recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colourless · gray-white · light yellow · colourless in transmitted light.
Streak
White
Cleavage
Perfect

On (100) perfect; on (211) and (001) in traces.

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
2.11 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 76° · 2V calc = 74°
Refractive index
1.412 – 1.543
Surface relief
Low
Principal indices
nα 1.412 – 1.417 · nβ 1.492 – 1.494 · nγ 1.540 – 1.543
Dispersion
relatively strong
Extinction
X = b; Z ∧ c = 83°.
UV response
May fluoresce under SW UV.
Michel-Lévy diagramhighlighted lineδ = 0.1270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1270 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1270 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 20.4218(9) Å · b = 3.4913(3) Å · c = 10.3326(6) Å
Cell angles
β = 106.452(4) °
Ratio a:b:c
1 : 0.171 : 0.506
Z
2
Morphology

Crystals elongated [010], also flattened (001). {h0l} faces striated parallel to [010]. Fibrous or massive columnar common.

Comment

Space Group: I2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
56.63%
11NaSodiumSodium322.99068.970
30.51%
6CCarbonCarbon212.01124.022
10.63%
1HHydrogenHydrogen51.0085.040
2.23%
Total226.024100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ägyptisches Natrium
  • Alkali orientale impurum terrestre
  • Natrum von Tripole
  • Stralige Natrum
  • Tronit
  • Tronita
  • Tronite
  • Urao

In other languages

French
Trona
German
Trona
Spanish
natrita · Trona
Italian
Trona
Portuguese
trona
Japanese
トロナ
Russian
Трона
Arabic
ترونا

Classification

Strunz
10th ed.

5.CB.15

  • 5CarbonatesClass
  • 5.CCarbonates without additional anions, with H2ODivision
  • 5.CBWith large cations (alkali and alkali-earth carbonates)Group
  • 5.CB.15TronaSpecies
Dana
8th ed.

13.01.04.01

  • 13Acid CarbonatesClass
  • 13.01MiscellaneousType
  • 13.01.04— unnamed intermediate level —Group
  • 13.01.04.01TronaSpecies
CIM

11.1.6

  • 11CarbonatesClass
  • 11.1Carbonates of the alkali metals and ammoniumGroup
  • 11.1.6TronaSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1747Wallerius, J.G. (1747) Mineralogia, eller Mineralriket. Stockholm: 174 (as Alkali orientale impurum terrestre).
  2. 1773Bagge, C. (1773) Om trona, eller ett slags natron, som finnes i Konungariket Tripoli i Barbariet. Kongl. Vetenskaps Academiens Handlingar, 34, 140-143.
  3. 1802Klaproth, M. H. (1802) LXXVIII. Untersuchung des straligen Natrum. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.83-88.
  4. 1826de Rivero, M., Boussingault, J.-B. (1826) Mémoire sur l'urao (carbonate de soude). Annales des mines, 12, 278-279. (as Urao)
  5. 1826Haidinger, (1826) Sur le carbonate de soufre natif. Annales des mines, 12, 279-281.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Trona — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/trona-4031},
  note      = {Accessed 2026-05-11}
}