Tripuhyite

Fe3+Sb5+O4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tpy
Discovered
1897
Also known as
  • Flajolotite
  • IMA1987-022
  • Squawcreekit
  • +3 more

Where it forms, where it's found

Type locality
Tripuí
  1. Ouro Preto
  2. Minas Gerais
  3. Brazil

-20.3871°, -43.5410°

80recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Yellowish brown · lemon-yellow · brown-black
Streak
Canary-yellow to dark brown with a greenish tinge.
Density
5.82 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.19 – 2.33
Surface relief
Very high
Principal indices
nω 2.19 · nε 2.33
Notes

Biaxial (+), anomalous. α = 2.19(1) β = 2.20(1) γ = 2.33(1) 2V(meas.) = Small.

Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
P42/mnm
Cell parameters
a = 4.625(4) Å · c = 3.059(5) Å
Z
1
Morphology

Fibrous; very fine-grained aggregates; globular.

Type-locality form

Microcrystalline aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony1121.760121.760
50.40%
8OOxygenOxygen415.99963.996
26.49%
26FeIronIron155.84555.845
23.11%
Total241.601100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Flajolotite
  • IMA1987-022
  • Squawcreekit
  • Squawcreekita
  • Tripuhyiet
  • Tripuhyte

In other languages

French
Tripuhyite
German
IMA 1987-022 · Tripuhyit
Spanish
Tripuhyita
Italian
Squawcreekite · tripuhyite
Portuguese
IMA1987-022 · Tripuhyíta

Classification

Strunz
10th ed.

4.DB.05

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DBWith medium-sized cations; chains of edge-sharing octahedraGroup
  • 4.DB.05TripuhyiteSpecies
Dana
8th ed.

44.02.01.03

  • 44AntimonatesClass
  • 44.02AX2O6Type
  • 44.02.01Bystromite GroupGroup
  • 44.02.01.03TripuhyiteSpecies
CIM

24.4.3

  • 24Antimonates and AntimonitesClass
  • 24.4Antimonates and antimonites of Mn and FeGroup
  • 24.4.3TripuhyiteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1897Hussak, E., Prior, G. T. (1897) On Tripuhyite, a New Antimonate of Iron, from Tripuhy, Brazil. Mineralogical Magazine and Journal of the Mineralogical Society, 11 (53) 302-303 doi:10.1180/minmag.1897.011.53.04 DOI: 10.1180/minmag.1897.011.53.04
  2. 1917Hussak, H. and Prior, G.T. (1917) Tripuhyte, um novo antimoniato de ferro de Tripuhy. Annaes da Escola de Minas de Ouro Preto, 15, 13-14.
  3. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  4. 1948Ahlfeld, Federico (1948) An unusual antimony deposit in Argentina. Economic Geology, 43 (7) 598-602 doi:10.2113/gsecongeo.43.7.598DOI: 10.2113/gsecongeo.43.7.598
  5. 1949Fleischer, M. (1949) New mineral names. American Mineralogist, 34 (1-2). 133-134
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tripuhyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tripuhyite-4024},
  note      = {Accessed 2026-05-11}
}