Argutite

GeO2
IMA status
  • Approved
IMA symbol
Agt
Discovered
1983
Also known as
  • Argutitt
  • IMA1980-067

Where it forms, where it's found

Geological setting

In a zinc deposit formed in metamorphosed lower Paleozoic sediments.

Type locality
Plan d'Argut deposit
  1. Argut-Dessous
  2. Saint-Gaudens
  3. Haute-Garonne
  4. Occitanie
  5. France

42.8931°, 0.7096°

13recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Density
6.28 g/cm³

Optical

Optical type
Uniaxial
Optical colour
Light grey; dark gray in oil.
Anisotropism
Distinct
Internal reflections
Frequent white to brownish internal reflections (the brown color likely due to enclosing sphalerite).
Reflectance R%
(14.8) 400 nm, (13.7) 420 nm, (12.6) 440 nm, (11.6) 460 nm, (11.2) 480 nm, (11.0) 500 nm, (11.0) 520 nm, (11.0) 540 nm, (11.0) 560 nm, (10.9) 580 nm, (10.9) 600 nm, (10.9) 620 nm, (10.9) 640 nm, (10.9) 660 nm, (11.0) 680 nm, (11.0) 700 nm
Notes

The optical properties are very close to those of cassiterite.

Reflected-light panel
11.5 %isotropic · single curve
Specimen sRGB 125, 86, 48
White reference100 % reflector under same lamp
Anisotropism
Distinct
Reflected colour
Light grey; dark gray in oil.
Internal reflections
Frequent white to brownish internal reflections (the brown color likely due to enclosing sphalerite).

Crystallography

Crystal system
Tetragonal
Space group
#190
Cell parameters
a = 4.3975 Å · c = 2.8625 Å
Z
2
Morphology

Crystals are showing (111), (100) and (101)

Twinning

Occasionally, on (101)

Type-locality form

Subhedral crystals to 20 µm, included in sphalerite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
32GeGermaniumGermanium172.63072.630
69.42%
8OOxygenOxygen215.99931.998
30.58%
Total104.628100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn
  • Mn
  • Fe

Synonyms

  • Argutitt
  • IMA1980-067

In other languages

French
Argutite
German
Argutit · IMA 1980-067
Spanish
Argutita
Italian
Argutite
Japanese
アルグ石

Classification

Strunz
10th ed.

4.DB.05

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DBWith medium-sized cations; chains of edge-sharing octahedraGroup
  • 4.DB.05ArgutiteSpecies
Dana
8th ed.

04.04.01.07

  • 04Simple OxidesClass
  • 04.04AX2Type
  • 04.04.01Rutile group (Tetragonal: P4/mnm)Group
  • 04.04.01.07ArgutiteSpecies
CIM

7.11.14

  • 7Oxides and HydroxidesClass
  • 7.11Oxides of Sn and PbGroup
  • 7.11.14ArgutiteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1956Baur, W. H. (1956) Über die Verfeinerung der Kristallstrukturbestimmung einiger Vertreter des Rutiltyps: TiO2, SnO2, GeO2 und MgF2 [On the refinement of the crystal structure determination of some representatives of the rutile type: TiO2, SnO2, GeO2 and MgF2]. Acta Crystallographica, 9 (6) 515-520 doi:10.1107/s0365110x56001388DOI: 10.1107/s0365110x56001388
  2. 1971Baur, W.H., Khan, A.A. (1971) Rutile-type compounds. IV. SiO2, GeO2 and a comparison with other rutile-type structures. Acta Crystallographica: B27: 2133-2139.
  3. 1983Johan, Z.; Oudin, E.; Picot, P. (1983) Analogues germanifères et gallifères des silicates et oxydes dans les gisements de zinc des Pyrénées centrales, France; argutite et carboirite, deux nouvelles espèces minérales [Germanium and gallium analogs of silicates and oxides from zinc deposits of the French central Pyrenees; argutite and carboirite, two new mineral species]. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 31 (1). 97-119 doi:10.1007/bf01084764DOI: 10.1007/bf01084764
  4. 1984Dunn, Pete J.; Cabri, Louis J.; Chao, George Y.; Fleischer, Michael; Francis, Carl A.; Grice, Joel D.; Jambor, John L.; Pabst, Adolf (1984) New mineral names. American Mineralogist, 69 (3-4). 406-412
  5. 1991Yamanaka, T., Ogata, K. (1991) Structure refinement of GeO2 polymorphs at high pressures and temperatures by energy-dispersive spectra of powder diffraction. Journal of Applied Crystallography: 24: 111-118.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Argutite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/argutite-330},
  note      = {Accessed 2026-05-11}
}