Villyaellenite

(Mn,Ca)Mn2Ca2(AsO3OH)2(AsO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Vy
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-008a
  • Villyaelleniet

Where it forms, where it's found

Type locality
Sainte-Marie-aux-Mines
  1. Colmar-Ribeauvillé
  2. Haut-Rhin
  3. Grand Est
  4. France

48.2458°, 7.1834°

10recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · orange to light pink
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

(100) good

Density
3.20 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70.5 – 76° · 2V calc = 75 – 75.6°
Refractive index
1.66 – 1.729
Surface relief
High
Principal indices
nα 1.660 – 1.713 · nβ 1.670 – 1.723 · nγ 1.676 – 1.729
Birefringence
0.016
Pleochroism
Visible

X=very pale orange pink, Y=exceedingly pale pink, Z=pale orange pink; Z>>X>Y.

Dispersion
weak
Extinction
Y ^ c = 30°-40°.
UV response
Not fluorescent.
Notes

Higher optics may represent closeness to end-member.

Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 18.55 Å · b = 9.50 Å · c = 9.99 Å
Cell angles
β = 96.94 °
Ratio a:b:c
1 : 0.512 : 0.539
Z
4
Morphology

Rosettes of prismatic crystals, elongated || [001], tabular || (100).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
34.98%
33AsArsenicArsenic474.922299.688
32.76%
25MnManganeseManganese354.938164.814
18.02%
20CaCalciumCalcium340.078120.234
13.14%
1HHydrogenHydrogen101.00810.080
1.10%
Total914.796100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn
  • Ca
  • Fe

Synonyms

  • IMA1983-008a
  • Villyaelleniet

In other languages

French
Villyaellenite
German
IMA 1983-008 · Villyaellenit
Italian
Villyaellenite
Chinese
水砷氢锰石

Classification

Strunz
10th ed.

8.CB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CBWith only medium-sized cations, RO4:H2O = 1:1Group
  • 8.CB.10VillyaelleniteSpecies
Dana
8th ed.

39.02.01.03

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.01Hureaulite GroupGroup
  • 39.02.01.03VillyaelleniteSpecies
CIM

20.8.20

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.8Arsenates of MnGroup
  • 20.8.20VillyaelleniteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1984Sarp, H. (1984) Villyaellenite, H2(Mn,Ca)5(AsO4)4·4H2O un nouveau minéral de Saint-Marie aux Mines (France). Schweizerische Mineralogische und Petrographische Mitteilungen: 64: 323-328.
  2. 1986Hawthorne, F.C., Bladh, K.W., Burke, E.A.J., Ercit, S., Grew, E.S., Grice, J.D., Puziewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 1543-1548.
  3. 1988Kampf, Anthony R., Ii, Charles R. Ross (1988) End-member villyaellenite from Mapimi, Durango, Mexico: Descriptive mineralogy, crystal structure, and implications for the ordering of Mn and Ca in type villyaellenite. American Mineralogist, 73 (9-10) 1172-1178
  4. 2007Roth, P. (2007) Villyaellenite. in Minerals first discovered in Switzerland and minerals named after Swiss individuals. Kristallografik Verlag (Achberg Germany) 202-203.
  5. 2009Kampf, A. R. (2009) Miguelromeroite, the Mn analogue of sainfeldite, and redefinition of villyaellenite as an ordered intermediate in the sainfeldite-miguelromeroite series. American Mineralogist, 94 (11) 1535-1540 doi:10.2138/am.2009.3278DOI: 10.2138/am.2009.3278
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Villyaellenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/villyaellenite-4182},
  note      = {Accessed 2026-05-11}
}