Vladimirivanovite

Na6Ca2[Al6Si6O24](SO4,S3,S2,Cl)2 · H2O
IMA status
  • Approved
IMA symbol
Vla
IMA approved
2011
Also known as
  • IMA2010-070
  • Lazurite-O
  • UM1976-26-SiOSO:AlCaClHNa
  • +1 more

Where it forms, where it's found

Geological setting

Calciphyres and marble.

Gem lazurite deposits

Type locality
Tultui lazurite deposit
  1. Malaya Bystraya River Valley
  2. Slyudyanka
  3. Russia

51.6578°, 103.3581°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark blue to ink-blue · light blue or greenish-blue to white

Similar colours to hauyne.

Streak
Blue to white
Tenacity
brittle
Cleavage

Distinct on (010).

Fracture
Step-Like
Density
2.48 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 63° · 2V calc = 66°
Refractive index
1.502 – 1.517
Surface relief
Moderate
Principal indices
nα 1.502 – 1.507 · nβ 1.509 – 1.514 · nγ 1.512 – 1.517
Pleochroism
Visible

Pleochroism: Light to dark blue; absorption: Z = Y > X

Dispersion
Weak.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 9.066(3) Å · b = 12.851(3) Å · c = 38.558(10) Å
Ratio a:b:c
1 : 1.417 : 4.253
Z
6
Type-locality form

Rims on lazurite, 0.01-3 mm thick, and elongated grains from 0.2-4 mm in size, and occasionally up to 15 x 20 mm. Rarely as veinlets up to 5 mm.

Comment

Space group Pnaa (non-standard setting).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3315.999527.967
34.42%
16SSulfurSulfur1232.060384.720
25.08%
14SiSiliconSilicon628.085168.510
10.98%
13AlAluminiumAluminium626.982161.892
10.55%
11NaSodiumSodium622.990137.940
8.99%
20CaCalciumCalcium240.07880.156
5.23%
17ClChlorineChlorine235.45070.900
4.62%
1HHydrogenHydrogen21.0082.016
0.13%
Total1534.101100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2010-070
  • Lazurite-O
  • UM1976-26-SiOSO:AlCaClHNa
  • Vladimirivanoviet

In other languages

German
IMA 2010-070 · Vladimirivanovit

Classification

Strunz
10th ed.

9.FB.10

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FBTektosilicates with additional anionsGroup
  • 9.FB.10VladimirivanoviteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1997Evsyunin, V.G., Sapozhnikov, A.N., Kashaev, A.A., Rastsvetaeva, R.K. (1997) Crystal structure of triclinic lazurite. Crystallography Reports, 42 (6) 938-945
  2. 1998Evsyunin, V.G., Rastsvetaeva, R.K., Sapozhnikov, A.N., Kashaev, A.A. (1998) Modulated structure of orthorhombic lazurite. Crystallography Reports, 43 (6) 999-1002
  3. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 8. Mineralogical Magazine, 75 (2) 289-294 doi:10.1180/minmag.2011.075.2.289 DOI: 10.1180/minmag.2011.075.2.289
  4. 2012Sapozhnikov, A. N., Kaneva, E. V., Cherepanov, D. I., Suvorova, L. F., Levitsky, V. I., Ivanova, L. A., Reznitsky, L. Z. (2012) Vladimirivanovite, Na6Ca2[Al6Si6O24](SO4,S3,S2,Cl)2 · H2O, a new mineral of sodalite group. Geology of Ore Deposits, 54 (7) 557-564 doi:10.1134/s1075701512070070DOI: 10.1134/s1075701512070070
  5. 2013(2013) Vladimirivanovite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vladimirivanovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vladimirivanovite-41155},
  note      = {Accessed 2026-05-11}
}