Ammonioalunite

(NH4)Al3(SO4)2(OH)6
IMA status
  • Approved
IMA symbol
Aalu
Discovered
1988
Also known as
  • Ammonioaluniet
  • Ammonioalunita
  • Ammonioalunitt
  • +1 more

Where it forms, where it's found

Geological setting

Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100 C.

Type locality
The Geysers
  1. West Mayacmas Mining District
  2. Sonoma County
  3. California
  4. USA

38.8019°, -122.8031°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Grayish white

colorless in thin section.

Streak
white
Cleavage
Perfect

perfect on (0001)(by analogy with the alunite group).

Density
2.4 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.59 – 1.602
Surface relief
Moderate
Principal indices
nω 1.590 · nε 1.602
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 7.01 Å · c = 17.88 Å
Z
3
Morphology

As rhombohedral crystals, to 20 μm, forming granular masses.

Type-locality form

As rhombohedral crystals, to 20 µm, forming granular masses.

Comment

Point Group: _3 2/m or 3m; Space Group: R_3m or R3m. a

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
56.97%
13AlAluminiumAluminium326.98280.946
20.59%
16SSulfurSulfur232.06064.120
16.31%
7NNitrogenNitrogen114.00714.007
3.56%
1HHydrogenHydrogen101.00810.080
2.57%
Total393.139100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ammonioaluniet
  • Ammonioalunita
  • Ammonioalunitt
  • IMA1986-037

In other languages

German
Ammonioalunit · IMA 1986-037
Italian
ammonioalunite

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10AmmonioaluniteSpecies
Dana
8th ed.

30.02.04.06

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.04Alunite Group (Alunite Subgroup)Group
  • 30.02.04.06AmmonioaluniteSpecies
CIM

25.1.10

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.10AmmonioaluniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1988Altaner, Stephen P., Fitzpatrick, Joan J., , M. Dennis Krohn, Bethke, Philip M., Hayba, Daniel O., Goss, James A., Brown, Zoe Ann (1988) Ammonium in alunites. American Mineralogist, 73 (1-2) 145-152
  2. 2005(2005) Ammonioalunite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2010Parafiniuk, J., Kruszewski, Ł. (2010) Minerals of the ammonioalunite—ammoniojarosite series formed on a burning coal dump at Czerwionka, Upper Silesian Coal Basin, Poland. Mineralogical Magazine, 74 (4) 731-745 doi:10.1180/minmag.2010.074.4.731DOI: 10.1180/minmag.2010.074.4.731
  4. 2010Bayliss, P., Kolitsch, U., Nickel, E. H., Pring, A. (2010) Alunite supergroup: recommended nomenclature. Mineralogical Magazine, 74 (5) 919-927 doi:10.1180/minmag.2010.074.5.919 DOI: 10.1180/minmag.2010.074.5.919
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ammonioalunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ammonioalunite-203},
  note      = {Accessed 2026-05-11}
}