Where it forms, where it's found
- Geological setting
Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100 C.
- Type locality
- The Geysers
- West Mayacmas Mining District
- Sonoma County
- California
- USA
38.8019°, -122.8031°
Physical
Optical
- Optical type
- Uniaxial (+)
- Refractive index
- 1.59 – 1.602
- Surface relief
- Moderate
- Principal indices
- nω 1.590 · nε 1.602
Crystallography
- Cell parameters
- a = 7.01 Å · c = 17.88 Å
- Z
- 3
- Morphology
As rhombohedral crystals, to 20 μm, forming granular masses.
- Type-locality form
As rhombohedral crystals, to 20 µm, forming granular masses.
- Comment
Point Group: _3 2/m or 3m; Space Group: R_3m or R3m. a
Chemical composition
Synonyms
- Ammonioaluniet
- Ammonioalunita
- Ammonioalunitt
- IMA1986-037
In other languages
- German
- Ammonioalunit · IMA 1986-037
- Italian
- ammonioalunite
Classification
7.BC.10
- 7SulfatesClass
- 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
- 7.BCWith medium-sized and large cationsGroup
- 7.BC.10AmmonioaluniteSpecies
30.02.04.06
- 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
- 30.02(AB)2(XO4)ZqType
- 30.02.04Alunite Group (Alunite Subgroup)Group
- 30.02.04.06AmmonioaluniteSpecies
25.1.10
- 25SulphatesClass
- 25.1Sulphates of the alkali metals and ammoniumGroup
- 25.1.10AmmonioaluniteSpecies
Group, growth & confusion
AluniteKAl3(SO4)2(OH)6Mineral—- Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Mineral—
ArgentojarositeAgFe3+3(SO4)2(OH)6Mineral—
Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Mineral—
Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Mineral—- DorallchariteTlFe3+3(SO4)2(OH)6Mineral—
- HuangiteCa0.5Al3(SO4)2(OH)6Mineral—
- Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Mineral—
JarositeKFe3+3(SO4)2(OH)6Mineral—
NatroaluniteNaAl3(SO4)2(OH)6Mineral—
Literature, links & citation
- 1988Altaner, Stephen P., Fitzpatrick, Joan J., , M. Dennis Krohn, Bethke, Philip M., Hayba, Daniel O., Goss, James A., Brown, Zoe Ann (1988) Ammonium in alunites. American Mineralogist, 73 (1-2) 145-152
- 2005(2005) Ammonioalunite. Handbook of Mineralogy. Mineralogical Society of America
- 2010Parafiniuk, J., Kruszewski, Ł. (2010) Minerals of the ammonioalunite—ammoniojarosite series formed on a burning coal dump at Czerwionka, Upper Silesian Coal Basin, Poland. Mineralogical Magazine, 74 (4) 731-745 doi:10.1180/minmag.2010.074.4.731DOI: 10.1180/minmag.2010.074.4.731
- 2010Bayliss, P., Kolitsch, U., Nickel, E. H., Pring, A. (2010) Alunite supergroup: recommended nomenclature. Mineralogical Magazine, 74 (5) 919-927 doi:10.1180/minmag.2010.074.5.919 DOI: 10.1180/minmag.2010.074.5.919
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Ammonioalunite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/ammonioalunite-203},
note = {Accessed 2026-05-11}
}