Alunite

KAl3(SO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Alu
Discovered
1824
Also known as
  • Alaun-Grammit
  • Alaunspat
  • Alaunstein (of Werner)
  • +25 more

Where it forms, where it's found

Geological setting

Formed between 15°C and 400°C by the action of sulfate, which may be generated from pyrite or solfataric action, on aluminous rocks, commonly accompanied by kaolinitization and silicification.

Type locality
Allumiere Quarries
  1. Allumiere
  2. Metropolitan City of Rome Capital
  3. Lazio
  4. Italy
1,151recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
white · pale shades of gray · yellow · red · to reddish brown

Colorless if pure

Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

On (0001), distinct; on (0112), traces. Handbook of mineralogy: On (0001), perfect

Fracture
Irregular/Uneven · Splintery · Conchoidal
Density
2.6 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.572 – 1.592
Surface relief
Moderate
Principal indices
nω 1.572 · nε 1.592
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 6.98 Å · c = 17.32 Å
Morphology

Rarely in small crystals; as druses in massive material or as aggregates. Crystals tabular (0001) or terminated by flat vicinal rhombohedra; rhombohedral and commonly pseudo-cubic (0112). Lenticular based on distortion or vicinal development. Massive, granular to dense. As rocky, admixed masses.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
54.08%
13AlAluminiumAluminium326.98280.946
19.54%
16SSulfurSulfur232.06064.120
15.48%
19KPotassiumPotassium139.09839.098
9.44%
1HHydrogenHydrogen61.0086.048
1.46%
Total414.198100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na
  • Fe

Synonyms

  • Alaun-Grammit
  • Alaunspat
  • Alaunstein (of Werner)
  • Alum de Rome
  • Alumen de Tolpha
  • Aluminilit
  • Aluminilita
  • Aluminilite
  • Alumite
  • Alumstone
  • Calafatite
  • Ignatiewite
  • K-Alunit
  • K-Alunite
  • Kalioalunit
  • Kalioalunita
  • Kalioalunite
  • Lœvigit
  • Lœvigita
  • Lœvigite
  • Lœwigit
  • Lœwigita
  • Lœwigite
  • Lowigit
  • Lowigita
  • Löwigite
  • Pierre alumineuse de la Tolfa
  • Romersk Alunsten

In other languages

French
alunite
German
Alaunspat · Alaunstein · Alunit · Lœvigit · Lœwigit
Spanish
alunita
Italian
alunite
Portuguese
Alunita · alunite
Japanese
明礬石
Chinese
明礬石
Russian
алунит
Arabic
ألونيت

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10AluniteSpecies
Dana
8th ed.

30.02.04.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.04Alunite Group (Alunite Subgroup)Group
  • 30.02.04.01AluniteSpecies
CIM

25.6.18

  • 25SulphatesClass
  • 25.6Sulphates of Al and TlGroup
  • 25.6.18AluniteSpecies

Group, growth & confusion

Often grow together
9 minerals

Literature, links & citation

Citations
  1. 1565Gesner C. (1565) Alumen. De omni rerum fossilium genere, gemmis, lapidibus, metallis, etc. Tiguri: 13. [as Alumen de Tolpha]
  2. 1747Wallerius, J.G (1747) Mineralogia, eller Mineralriket. Stockholm: 163. [as Romersk Alunsten]
  3. 1797Delamétherie, J.C. (1797) Théorie de la Terre, 2nd. Edition, 5 volumes, Paris: 2: 113. [as Aluminilite]
  4. 1801Haüy, René Just (1801) Traité de Minéralogie (1st ed.) Vol. 2. Chez Louis.
  5. 1804Jameson, Robert (1804) System of Mineralogy (1st ed.) Robert Jameson, Edinburgh.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alunite-161},
  note      = {Accessed 2026-05-11}
}