Ammoniojarosite

(NH4)Fe3+3(SO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ajrs
Discovered
1927
Also known as
  • Ammoniojarosiet
  • Ammoniojarosita
  • Ammoniojarositt
  • +1 more

Where it forms, where it's found

Geological setting

Formed in black lignitic shales containing pyrite.

Type locality
Kaibab fault
  1. Kane County
  2. Utah
  3. USA
32recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light yellow · light yellow to nearly colourless in transmitted light.
Density
3.112 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.75 – 1.8
Surface relief
High
Principal indices
nω 1.8 · nε 1.75
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 7.32 Å · c = 17.5 Å
Morphology

Small lumps and irregular flattened nodules comprised of microscopic tabular grains with hexagonal outlines at times.

Type-locality form

Small lumps and hard irregular flattened nodules up to 4 cm across by 5 mm thick embedded in blackish-brown lignitic material. With magnification, it is seen to form minute, transparent, pale-yellow, tabular grains including a few showing hexagonal outlines.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
46.69%
26FeIronIron355.845167.535
34.92%
16SSulfurSulfur232.06064.120
13.37%
7NNitrogenNitrogen114.00714.007
2.92%
1HHydrogenHydrogen101.00810.080
2.10%
Total479.728100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ammoniojarosiet
  • Ammoniojarosita
  • Ammoniojarositt
  • Ammonium jarosite

In other languages

German
Ammoniojarosit
Italian
ammoniojarosite

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10AmmoniojarositeSpecies
Dana
8th ed.

30.02.05.04

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.05Alunite Group (Jarosite Subgroup)Group
  • 30.02.05.04AmmoniojarositeSpecies
CIM

25.11.14

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.14AmmoniojarositeSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1927Shannon, Earl V. (1927) Ammoniojarosite, a new mineral of the jarosite group from Utah. American Mineralogist, 12 (12) 424-426
  2. 1929Shannon, E.V. (1929) Proceedings of the U.S. National Museum: 74[13].
  3. 1937Hendricks, Sterling B. (1937) The crystal structure of alunite and the jarosites. American Mineralogist, 22 (6) 773-784
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1973Smith, W. L., Lampert, J. E. (1973) Crystal data for ammoniojarosite. NH4Fe3(OH)6(SO4)2. Journal of Applied Crystallography, 6 (6) 490-491 doi:10.1107/s0021889873009301DOI: 10.1107/s0021889873009301
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ammoniojarosite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ammoniojarosite-205},
  note      = {Accessed 2026-05-11}
}