Natroalunite

NaAl3(SO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nalu
Discovered
1902
Also known as
  • Alkanasul
  • Almeriit
  • Almeriita
  • +8 more

Where it forms, where it's found

Type locality
Red Mountain Mining District
  1. Colorado
  2. USA
143recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
White · grayish · yellowish · reddish · red-brown · colourless in transmitted light.

White when pure.

Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

On (0001), distinct; on (0112), traces.

Fracture
Irregular/Uneven · Splintery · Conchoidal
Density
2.6 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.568 – 1.59
Surface relief
Moderate
Principal indices
nω 1.568 · nε 1.59
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 6.97 Å · c = 16.74 Å
Morphology

Rarely in small crystals; as druses in massive material or as aggregates. Crystals tabular (0001) or terminated by flat vicinal rhombohedra; rhombohedral and commonly pseudo-cubic (0112). Lenticular based on distortion or vicinal development. Massive, granular to dense.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
56.27%
13AlAluminiumAluminium326.98280.946
20.33%
16SSulfurSulfur232.06064.120
16.11%
11NaSodiumSodium122.99022.990
5.77%
1HHydrogenHydrogen61.0086.048
1.52%
Total398.090100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K

Synonyms

  • Alkanasul
  • Almeriit
  • Almeriita
  • Almeriite
  • Alumian
  • Alumianit
  • Alumianita
  • Alumianite
  • Natroaluniet
  • Natroalunite-1c
  • Soda-Alunite

In other languages

German
Natroalunit
Spanish
almeriita · natroalunita
Italian
natroalunite

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10NatroaluniteSpecies
CIM

25.6.15

  • 25SulphatesClass
  • 25.6Sulphates of Al and TlGroup
  • 25.6.15NatroaluniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1894Hurlbutt, E.B. (1894) On alunite, from Red Mountain, Ouray County, Colorado. American Journal of Science: 48: 130-131.
  2. 1902Hillebrand, W.F., Penfield, S.L. (1902) Some additions to the alunite-jarosite group of minerals. American Journal of Science: 164: 211-220.
  3. 1910Calderón y Arana, S. (1910) Los minerales de España, 2 volumes, Madrid: 2: 203 (as Almeriite).
  4. 1911Schaller, W.T. (1911) The alunite-beudantite group. American Journal of Science: 32: 359-364.
  5. 1927Doelter, C. (1927) Handbuch der Mineral-chemie (in 4 volumes divided into parts): 4 [2]: 495 (as Natroalunit).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natroalunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natroalunite-2850},
  note      = {Accessed 2026-05-11}
}