Jarosite

KFe3+3(SO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Jrs
Discovered
1852
Also known as
  • Antunesit
  • Antunesita
  • Antunesite
  • +11 more

History

A small yellow flower gave this mineral its name. Jara is the Spanish word for a yellow-flowered shrub of the genus Cistus that grows across the dry hills of southern Spain. One ravine thick with it, the Barranco del Jaroso in the Sierra Almagrera, became the place where the mineral was first found.

In 1852 the German mineralogist Johann Friedrich August Breithaupt described jarosite from that ravine and named it for the locality. The site sits near Cuevas del Almanzora in Almería, in Spain's far south. The mineral is a sulfate — a compound built around sulfate groups — of potassium and iron, and it forms in acidic, iron-rich settings where sulfide ores have weathered.

People had brushed against the mineral long before they named it. Clay spheres coated in jarosite were found buried beneath the Temple of the Feathered Serpent at Teotihuacan in central Mexico.

For most of the next century after Breithaupt, jarosite stayed a minor curiosity of mine dumps and weathered outcrops. Then a robot found it on another planet.

In 2004 the rover Opportunity detected jarosite at Meridiani Planum, the broad Martian plain where it had landed. The find came from the rover's Mössbauer spectrometer, an instrument that identifies iron-bearing minerals. The detection mattered because jarosite forms only in dilute sulfuric acid in groundwater. Its presence was strong evidence that acidic liquid water had once stood on the Martian surface. The geologist Roger Burns had predicted the find years earlier. Spirit and Curiosity later detected the same mineral elsewhere on Mars.

Industrial & practical applications

Almost nobody mines jarosite. It has no role as a gemstone, a pigment of any scale, or an ore, and it is not a sought commodity. Where it matters to industry, it appears as a waste product rather than a goal.

That role is in zinc refining. Extracting zinc from its ore by chemistry rather than smelting — a route called hydrometallurgy — leaves dissolved iron in the liquid, and the iron must come out before the zinc can be recovered. The standard way to remove it is the jarosite precipitation process, the most extensively used iron-removal method in the industry. Iron is forced to crystallise out of the weakly acidic solution as jarosite. The resulting solid cake is pulled from the circuit and stockpiled as a tailing — mine waste held on site.

The volumes are large, which makes disposal the real story. Roughly half a tonne of jarosite residue is generated for every tonne of zinc produced, and the residue counts as hazardous waste because it carries heavy metals. Handling and storing it is a recognised burden on the industry rather than a source of value.

Beyond that, jarosite is of interest mainly to scientists and collectors — as a marker of acidic weathering on Earth, and as the Martian mineral that signalled past liquid water.

Where it forms, where it's found

Geological setting

A secondary mineral found in the oxidized zones of sulfide deposits, forming by the reaction of dilute sulfuric acid in groundwater, derived from the oxidation of pyrite, with gangue minerals and wall rock in the deposits.

Type locality
Jaroso Ravine
  1. Sierra Almagrera
  2. Cuevas del Almanzora
  3. Almería
  4. Andalusia
  5. Spain

37.2975°, -1.7508°

2,474recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous (Glassy)
Transparency
Translucent
Colour
Amber-yellow · yellow-brown · to brown or light yellow.
Streak
Pale-yellow
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (0001).

Fracture
Irregular/Uneven · Conchoidal
Density
2.9 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.713 – 1.82
Surface relief
High
Principal indices
nω 1.815 – 1.82 · nε 1.713 – 1.715
Pleochroism
Visible

Ε (X) = Colourless (Y) = Reddish brown Ο (Z) = Reddish brown

Luminescence
None
Notes

Commonly anomalously biaxial with a very small 2V and sectional development.

Michel-Lévy diagramhighlighted lineδ = 0.1035
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1035 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1035 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 7.304 Å · c = 17.268 Å
Z
3
Morphology

Crystals usually tiny, pseudocubic {01-13} or tabular (0001). Typically found as granular crusts, it may also be in nodules or fibrous masses, powdery to earthy, or concretionary.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
44.73%
26FeIronIron355.845167.535
33.45%
16SSulfurSulfur232.06064.120
12.80%
19KPotassiumPotassium139.09839.098
7.81%
1HHydrogenHydrogen61.0086.048
1.21%
Total500.787100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na
  • Ag
  • Pb

Synonyms

  • Antunesit
  • Antunesita
  • Antunesite
  • Antunezit
  • Antunezita
  • Antunezite
  • Antunit
  • Jarosite (of Breithaupt)
  • Leucanterit
  • Leucanterita
  • Leucanterite
  • Moronolite
  • Pastréit
  • Vitriolgelb

In other languages

French
Antunezite · Jarosite · Leucantérite · Misy · Moronolite · Utahite · Vitriolgelb
German
Jarosit · Maibolt · Raimondit
Spanish
Jarosita
Italian
jarosite
Portuguese
jarosita · Jarosite
Japanese
鉄明ばん石 · 鉄明礬石
Chinese
黃鉀鐵礬 · 黄钾铁矾
Traditional Chinese
黃鉀鐵礬
Russian
Ярозит

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10JarositeSpecies
Dana
8th ed.

30.02.05.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.05Alunite Group (Jarosite Subgroup)Group
  • 30.02.05.01JarositeSpecies
CIM

25.11.9

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.9JarositeSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1838Rammelsberg (1838) Annalen der Physik, Halle, Leipzig: 43: 132 (as Gelbeisenerz).
  2. 1845Haidinger, Wm. (1845) 512 (as Misy).
  3. 1847Hausmann, J.F.L. (1847) Handbuch der Mineralogie 3 volumes, Göttingen. Second edition: vol. 2, in two parts: 1205 (as Vitriolgelb).
  4. 1852Breithaupt (1852) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig (merged into Glückauf): 6: 68 (as Jarosit).
  5. 1857Shepard C.U. (1857) Treatise on Mineralogy, third edition: vol. 2: 4 (suppl. app.) (as Moronolite).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Jarosite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/jarosite-2078},
  note      = {Accessed 2026-05-11}
}