Arakiite

ZnMn2+12Fe3+2(As3+O3)(As5+O4)2(OH)23
IMA status
  • Approved
IMA symbol
Ark
Also known as
  • Arakiiet
  • Arakiitt
  • IMA1998-062

Where it forms, where it's found

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous · Metallic
Transparency
Translucent · Opaque
Colour
Red-brown to orange-brown
Streak
Pale-brown, red-brown
Tenacity
brittle
Cleavage
Perfect

Perfect on (001).

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.41 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 40 – 44° · 2V calc = 54°
Refractive index
1.723 – 1.75
Surface relief
High
Principal indices
nα 1.723 · nβ 1.744 · nγ 1.750
Birefringence
0.027
Pleochroism
Not Visible
Dispersion
r > v medium
UV response
No fluorescence under SW or LW UV.
Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cc
Cell parameters
a = 14.248(8) Å · b = 8.228(4) Å · c = 24.23(1) Å
Cell angles
β = 93.62(3) °
Ratio a:b:c
1 : 0.577 : 1.701
Unit cell volume
2843 ų
Z
4
Morphology

Predominantly anhedral, mica-like.

Twinning

None observed

Type-locality form

Thin foliated reddish-colored masses on ore-bearing matrix. Megascopically indistinguishable from dixenite and hematolite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese1254.938659.256
40.49%
8OOxygenOxygen3415.999543.966
33.41%
33AsArsenicArsenic374.922224.766
13.80%
26FeIronIron255.845111.690
6.86%
30ZnZincZinc165.38065.380
4.02%
1HHydrogenHydrogen231.00823.184
1.42%
Total1628.242100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arakiiet
  • Arakiitt
  • IMA1998-062

In other languages

German
Arakiit · IMA 1998-062
Italian
Arakiite
Chinese
荒木石

Classification

Strunz
10th ed.

8.BE.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.45ArakiiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1999Cooper, Mark A., Hawthorne, Frank C. (1999) The effect of differences in coordination on ordering polyvalent cations in close-packed structures; the crystal structure of arakiite and comparison with hematolite. The Canadian Mineralogist, 37 (6). 1471-1482
  2. 2000Roberts, Andrew C., Grice, Joel D., Hawthorne, Frank C., Cooper, Mark A., Feinglos, Mark N. (2000) Arakiite, a New Zn-Bearing Hematolite-like Mineral from Långban, Värmland, Sweden. The Mineralogical Record, 31 (3) 253-256
  3. 2001Jambor, John L., Kovalenker, Vladimir A., Roberts, Andrew C. (2001) New mineral names. American Mineralogist, 86 (3). 376-379
  4. 2001Mandarino, Joseph A. (2001) New minerals. The Canadian Mineralogist, 39 (5) 1473-1502 doi:10.2113/gscanmin.39.5.1473 DOI: 10.2113/gscanmin.39.5.1473
  5. 2017(2017) Arakiite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arakiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arakiite-6805},
  note      = {Accessed 2026-05-11}
}