Mcgovernite

Zn3(Mn2+,Mg,Fe3+,Al)42(As3+O3)2(As5+O4)4[(Si,As5+)O4]8(OH)42
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mgv
Discovered
1927
Also known as
  • Macgovernite
  • Mcgoverniet

Where it forms, where it's found

Geological setting

Filling veinlets traversing lean franklinite-zincite ore rich in calcite.

Type locality
Sterling Mine
  1. Sterling Hill
  2. Ogdensburg
  3. Sussex County
  4. New Jersey
  5. USA

41.0836°, -74.6047°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bronzy-brown · deep red-brown
Cleavage
Perfect

Micaceous on (0001)

Density
3.719 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.757 – 1.76
Surface relief
High
Principal indices
nω 1.757 · nε 1.76
UV response
None.
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#85
Cell parameters
a = 8.190254(12) Å · c = 203.6215(2) Å
Unit cell volume
11829 ų
Z
6
Morphology

Aggregates of micaceous plates and radial aggregates of platy crystals.

Type-locality form

Uniformly granular mass of coarse grain, the individual grains showing an almost micaceous cleavage.

Comment

Unit cell from Lake and Von Dreele (2025); a = 8.22, c = 203.15 Å were given by Hawthorne (2018). Space group R3c or R_3c. (Hawthorne, 2018); Lake and Von Dreele (2025) conclude it is R3c (non-centrosymmetric).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron4255.8452345.490
23.80%
25MnManganeseManganese4254.9382307.396
23.41%
8OOxygenOxygen9615.9991535.904
15.59%
13AlAluminiumAluminium4226.9821133.244
11.50%
33AsArsenicArsenic1474.9221048.908
10.64%
12MgMagnesiumMagnesium4224.3051020.810
10.36%
14SiSiliconSilicon828.085224.680
2.28%
30ZnZincZinc365.380196.140
1.99%
1HHydrogenHydrogen421.00842.336
0.43%
Total9854.908100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • H20

Synonyms

  • Macgovernite
  • Mcgoverniet

In other languages

German
Mcgovernit
Italian
Mcgovernite

Classification

Strunz
10th ed.

8.BE.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.45McgoverniteSpecies
Dana
8th ed.

43.04.09.01

  • 43Compound Phosphates, Etc.Class
  • 43.04Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.04.09Mcgovernite GroupGroup
  • 43.04.09.01McgoverniteSpecies
CIM

17.7.10

  • 17Silicates Containing other AnionsClass
  • 17.7Silicates with vanadate, arsenate or antimonateGroup
  • 17.7.10McgoverniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1927Palache, C., Bauer, L. H. (1927) McGovernite, a new mineral from Sterling Hill, New Jersey. American Mineralogist, 12 (10) 373-374
  2. 1960Wuensch, Berhhardt J. (1960) The crystallography of mcgovernite, a complex arsenosilicate. American Mineralogist, 45 (9-10) 937-945
  3. 1978Moore, Paul B., Araki, Takaharu (1978) Hematolite: a complex dense-packed sheet structure. American Mineralogist, 63 (1-2) 150-159
  4. 1980Dunn, Pete J., Nelen, Joseph A. (1980) Kraisslite and mcgovernite: new chemical data. American Mineralogist, 65 (9-10) 957-960
  5. 1988Dunn, Pete J., Francis, Carl A., Innes, John (1988) A mcgovernite-like mineral and leucophoenicite from the Kombat mine, Namibia. American Mineralogist, 73 (9-10) 1182-1185
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mcgovernite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mcgovernite-2614},
  note      = {Accessed 2026-05-11}
}