Dixenite

Cu1+Fe3+Mn2+14(As5+O4)(As3+O3)5(SiO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dxn
Discovered
1920
Also known as
  • Dixeniet

Where it forms, where it's found

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Deep red-brown to nearly black
Cleavage
Perfect

basal micaceous

Density
4.35 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.73 – 1.97
Surface relief
Very high
Principal indices
nω 1.97 · nε 1.73
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.2400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2400 nm5th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2400 nm
Order5th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#78
Cell parameters
a = 8.233(4) Å · c = 37.499(1) Å
Z
3
Morphology

in aggregates of thin flakes, massive

Type-locality form

Aggregates of thin flakes without crystal outlines.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese1454.938769.132
39.89%
8OOxygenOxygen3315.999527.967
27.38%
33AsArsenicArsenic674.922449.532
23.31%
29CuCopperCopper163.54663.546
3.30%
14SiSiliconSilicon228.08556.170
2.91%
26FeIronIron155.84555.845
2.90%
1HHydrogenHydrogen61.0086.048
0.31%
Total1928.240100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Ca
  • Na
  • K
  • P

Synonyms

  • Dixeniet

In other languages

German
Dixenit
Spanish
dixenita
Italian
Dixenite

Classification

Strunz
10th ed.

8.BE.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.45DixeniteSpecies
Dana
8th ed.

46.02.08.01

  • 46Antimonites and Arsenites Containing Hydroxyl or HalogenClass
  • 46.02MiscellaneousType
  • 46.02.08Dixenite GroupGroup
  • 46.02.08.01DixeniteSpecies
CIM

17.7.8

  • 17Silicates Containing other AnionsClass
  • 17.7Silicates with vanadate, arsenate or antimonateGroup
  • 17.7.8DixeniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1920Flink, Gustaf (1920) Trigonit och Dixenit, två nya mineral från Långbanshytte gruvor. Geologiska Föreningen i Stockholm Förhandlingar, 42 (7) 436-452 doi:10.1080/11035892009444477 DOI: 10.1080/11035892009444477
  2. 1921Wherry, E.T. (1921) New minerals. American Mineralogist: 6: 92-95.
  3. 1969Welin, E. (1969) Notes on the mineralogy of Sweden 6. X-ray powder data for minerals from Långban and the related mineral deposits of Central Sweden. Arkiv för Mineralogi och Geologi, 4 (6, nr 30). 499-541
  4. 1981Araki, T., Moore, P.B. (1981): Dixenite, Cu+Mn2+14Fe3+(OH)6(As3+O3)5(Si4+O4)2(As5+O4) : metallic [As3+4Cul+] clusters in an oxide matrix. American Mineralogist: 66: 1263-1273.
  5. 2001(2001) Dixenite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dixenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dixenite-1298},
  note      = {Accessed 2026-05-11}
}