Barbosalite

Fe2+Fe3+2(PO4)2(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bsa
Discovered
1954
Also known as
  • Barbosaliet
  • Ferro-ferri-lazulite

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Sapucaia mine
  1. Sapucaia do Norte
  2. Galiléia
  3. Minas Gerais
  4. Brazil

-18.9008°, -41.4844°

36recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Black to dark blue-green · green · blue green · green blue · greenish black · black
Streak
Dark blue to dark green
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal · Sub-Conchoidal
Density
3.60 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 64 – 70°
Refractive index
1.76 – 1.84
Surface relief
Very high
Principal indices
nα 1.76 – 1.78 · nβ 1.77 – 1.81 · nγ 1.835 – 1.84
Birefringence
0.075
Pleochroism
Visible

X = Y = dark blue green; Z = dark olive green.

Dispersion
r > v strong
UV response
Not fluorescent in UV
Notes

Absorption: X = Y > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0750
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]750 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation750 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 7.31 Å · b = 7.48 Å · c = 7.52 Å
Cell angles
β = 120.15 °
Ratio a:b:c
1 : 1.023 : 1.029
Unit cell volume
349.94 ų
Z
2
Morphology

Blocky to rectangular prismatic crystal, also botryoidal.

Twinning

Contact twins with (001) as composition surface.

Type-locality form

Black drusy crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron355.845167.535
42.79%
8OOxygenOxygen1015.999159.990
40.87%
15PPhosphorusPhosphorus230.97461.948
15.82%
1HHydrogenHydrogen21.0082.016
0.52%
Total391.489100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Barbosaliet
  • Ferro-ferri-lazulite

In other languages

German
Barbosalith
Spanish
Barbosalita
Italian
Barbosalite
Chinese
复铁天蓝石

Classification

Strunz
10th ed.

8.BB.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.40BarbosaliteSpecies
Dana
8th ed.

41.10.01.04

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.10(AB)3(XO4)2ZqType
  • 41.10.01Lazulite GroupGroup
  • 41.10.01.04BarbosaliteSpecies
CIM

19.13.1

  • 19PhosphatesClass
  • 19.13Phosphates of Fe aloneGroup
  • 19.13.1BarbosaliteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
2 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1954Lindberg, M. L., Pecora, W. T. (1954) Tavorite and barbosalite: two new phosphate minerals from Minas Gerais, Brazil. Science, 119 (3099) 739 doi:10.1126/science.119.3099.739DOI: 10.1126/science.119.3099.739
  2. 1955Lindberg, M. L., Pecora, W. T. (1955) Tavorite and barbosalite, two new phosphate minerals from Minas Gerais, Brazil. American Mineralogist, 40 (11-12) 952-966
  3. 1959Lindberg, M. L., Christ, C. L. (1959) Crystal structures of the isostructural minerals lazulite, scorzalite and barbosalite. Acta Crystallographica, 12 (9) 695-697 doi:10.1107/s0365110x5900202xDOI: 10.1107/s0365110x5900202x
  4. 1966Bhaskara Rao, A., Adusumilli, Maria S. (1966) Leucophosphite and barbosalite from north-east Brazil. Mineralogical Magazine and Journal of the Mineralogical Society, 35 (273) 784-785 doi:10.1180/minmag.1966.035.273.17 DOI: 10.1180/minmag.1966.035.273.17
  5. 1968van Wambeke, L. (1968) Quelques nouveaux minéraux phosphates du Congo: la landesite-(Fe), la barbosalite et la triplite. Bulletin de la Société Belge de Géologie de Paléontologie & d'Hydrologie, 77. 191-200
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barbosalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barbosalite-516},
  note      = {Accessed 2026-05-11}
}