Phosphosiderite

Fe3+(PO4) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Phsd
Discovered
1890
Also known as
  • Clinobarrandite
  • Clinostrengit
  • Clinostrengite
  • +5 more

Where it forms, where it's found

Geological setting

Alteration product of triphylite.

Alteration product of triphylite in granitic pegmatites, soils, replcement mineral in bones and shells.

Type locality
Kalterborn Mine
  1. Eiserfeld
  2. Siegen
  3. Siegen-Wittgenstein
  4. Arnsberg
  5. North Rhine-Westphalia
  6. Germany
200recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Purple to reddish violet · rose-red · peachy-pink · brownish yellow · moss-green · colourless · rose to colourless in transmitted light.
Tenacity
brittle
Cleavage
Distinct/Good

On (010), good; on (001), indistinct.

Fracture
Irregular/Uneven
Density
2.74 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 62 – 66° · 2V calc = 62°
Refractive index
1.692 – 1.739
Surface relief
High
Principal indices
nα 1.692 – 1.703 · nβ 1.725 – 1.728 · nγ 1.738 – 1.739
Birefringence
0.046
Pleochroism
Visible

X = light rose; Y = carmine-red; Z = colourless.

Dispersion
r > v, very strong
Extinction
Y = b; X ∧ c = ∼4°.
Michel-Lévy diagramhighlighted lineδ = 0.0460
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]460 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation460 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.329 Å · b = 9.798 Å · c = 8.712 Å
Cell angles
β = 90.51 °
Ratio a:b:c
1 : 1.839 : 1.635
Z
4
Morphology

Crystals tabular (010) or stout prismatic [001]. Also occurs as botryoidal or reniform masses and crusts with a radial-fibrous structure. Forms include (001), (100), (010), (101), (110), (210), (410), (710), (111), (771), (011), (034), (041).

Twinning

On (101), commonly as interpenetration twins.

Type-locality form

Crystalline aggregates. Crystals to 4 cm, but with a rough surface and stepped structure.

Comment

Space Group: P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
51.37%
26FeIronIron155.84555.845
29.89%
15PPhosphorusPhosphorus130.97430.974
16.58%
1HHydrogenHydrogen41.0084.032
2.16%
Total186.845100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Mn

Synonyms

  • Clinobarrandite
  • Clinostrengit
  • Clinostrengite
  • Klinostrengit
  • Metastrengit
  • Metastrengita
  • Metastrengite
  • Phosphosideriet

In other languages

French
Phosphosidérite
German
Clinobarrandit · Clinostrengit · Metastrengit · Phosphosiderit
Italian
Fosfosiderite · Metastrengita, Clinostrengite

Classification

Strunz
10th ed.

8.CD.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CDWith only medium-sized cations, RO4:H2O = 1:2Group
  • 8.CD.05PhosphosideriteSpecies
Dana
8th ed.

40.04.03.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.04(AB)5(XO4)2·xH2OType
  • 40.04.03Metavariscite groupGroup
  • 40.04.03.02PhosphosideriteSpecies
CIM

19.13.3

  • 19PhosphatesClass
  • 19.13Phosphates of Fe aloneGroup
  • 19.13.3PhosphosideriteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1890Bruhns, Willy and Busz, Karl Heinrich Emil Georg (1890) Phosphosiderit, ein neues mineral von der Grube Kalterborn bei Eiserfeld im Siegenschen. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 17: 555-560.
  2. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  3. 1910Lacroix, A. (1910) Minéralogie de la France et de ses colonies Vol. 4. Library Polytechnique, Paris.
  4. 1915Laubmann, H.; Steinmetz, H. (1915) Phosphatführende Pegmatite des Oberpfälzer und Bayerischen Waldes. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 55 (1-6). 523-586 doi:10.1524/zkri.1915.55.1.523DOI: 10.1524/zkri.1915.55.1.523
  5. 1920(1920) Atlas Der Krystallformen Vol. 6 - Text - Band VI - Markasit-Pyrit. Carl Winters Universitätsbuchhandlung, Heidelberg.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphosiderite-3187},
  note      = {Accessed 2026-05-11}
}