Brushite

Ca(PO3OH) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bsh
Discovered
1864
Also known as
  • Epiglaubit
  • Epiglaubita
  • Epiglaubite
  • +2 more

Where it forms, where it's found

Geological setting

Cave guano deposit.

In biological phosphate as well as sedimentary phosphate deposits; incrustations on ancient bones and crypts. May form due to run-off from heavily fertilized fields.

Type locality
Aves Island
  1. Federal Dependencies
  2. Venezuela

15.6703°, -63.6187°

100recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · light yellow · colorless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (010) and (001), perfect.

Density
2.30 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 59 – 87° · 2V calc = 80°
Refractive index
1.539 – 1.552
Surface relief
Moderate
Principal indices
nα 1.539 – 1.540 · nβ 1.544 – 1.546 · nγ 1.551 – 1.552
Birefringence
0.012
Pleochroism
Non-pleochroic
Dispersion
r >v , crossed
Extinction
X ∧ c = 30°; Z = b.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cc
Cell parameters
a = 5.812(2) Å · b = 15.180(3) Å · c = 6.239(2) Å
Cell angles
β = 116.43(3) °
Ratio a:b:c
1 : 2.612 : 1.073
Z
4
Morphology

Crystals minute, acicular or prismatic to tabular (010). Efflorescences, cavity linings. Earthy, powdery, foliated.

Comment

Cell from Curry and Jones (1971).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
55.78%
20CaCalciumCalcium140.07840.078
23.29%
15PPhosphorusPhosphorus130.97430.974
18.00%
1HHydrogenHydrogen51.0085.040
2.93%
Total172.086100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Epiglaubit
  • Epiglaubita
  • Epiglaubite
  • Metabrushite
  • Stoffertite

In other languages

French
Brushite
German
Brushit · Epiglaubit
Spanish
Brushita
Italian
Brushite
Japanese
ブラシュ石 · ブラッシャイト · ブルッシャイト
Chinese
透磷钙石

Classification

Strunz
10th ed.

8.CJ.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.50BrushiteSpecies
Dana
8th ed.

39.01.01.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.01A[HXO4]·xH2OType
  • 39.01.01— unnamed intermediate level —Group
  • 39.01.01.01BrushiteSpecies
CIM

19.4.3

  • 19PhosphatesClass
  • 19.4Phosphates of CaGroup
  • 19.4.3BrushiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1856Shepard (1856) American Journal of Science: 22: 96 (as Epiglaubite).
  2. 1865Julien (1865) American Journal of Science: 40: 369 (as Metabrushite).
  3. 1865Moore (1865) American Journal of Science: 39: 43.
  4. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  5. 1897Lacroix, A. (1897) Sur la brushite et la métabrushite. Bulletin de la Société française de Minéralogie: 20: 112-118.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brushite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brushite-793},
  note      = {Accessed 2026-05-11}
}