Pharmacolite

Ca(AsO3OH) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pmc
Discovered
1800
Also known as
  • Arsenicit
  • Arsenicita
  • Arsenikbluethe
  • +5 more

Where it forms, where it's found

Geological setting

Found on oxidized arsenic ores; may be post-mining.

Oxidized zones of arsenical ore deposits.

Type locality
Sophia Mine
  1. Böckelsbach valley
  2. Wittichen
  3. Schenkenzell
  4. Rottweil
  5. Freiburg Region
  6. Baden-Württemberg
  7. Germany

48.3333°, 8.3333°

114recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Silky
Transparency
Transparent · Translucent
Colour
White or colorless · grayish white · colorless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (010), perfect.

Fracture
Irregular/Uneven
Density
2.53 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 77° · 2V calc = 84°
Refractive index
1.58 – 1.594
Surface relief
Moderate
Principal indices
nα 1.580 – 1.583 · nβ 1.589 – 1.590 · nγ 1.590 – 1.594
Birefringence
0.010
Pleochroism
Non-pleochroic
Dispersion
r > v
Extinction
Z=b; X ^ c = 29°
UV response
May be fluorescent pale blue in SW UV
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.9745 Å · b = 15.4340 Å · c = 6.2797 Å
Cell angles
β = 114.83 °
Ratio a:b:c
1 : 2.583 : 1.051
Z
4
Morphology

Crystals tiny, rare, flattened on (010) or needle-like [001]. Silky fibrous; acicular clusters; botryoidal and stalactitic.

Comment

Space group Ia (non-standard setting). If Z = 8, there is a similarity to krautite. Another setting is C-centered: a ~ 6.59, b ~ 15.43, c ~ 5.98 Å, β ~ 120.3°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
44.44%
33AsArsenicArsenic174.92274.922
34.68%
20CaCalciumCalcium140.07840.078
18.55%
1HHydrogenHydrogen51.0085.040
2.33%
Total216.034100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arsenicit
  • Arsenicita
  • Arsenikbluethe
  • Arsenikblüte
  • Arseniksaurer Kalk
  • Parmakit
  • Pharmacoliet
  • Pharmacolit

In other languages

French
pharmacolite
German
Pharmakolith
Spanish
farmacolita
Italian
farmacolite
Portuguese
farmacolite
Chinese
毒石
Russian
фармаколит

Classification

Strunz
10th ed.

8.CJ.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.50PharmacoliteSpecies
Dana
8th ed.

39.01.01.02

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.01A[HXO4]·xH2OType
  • 39.01.01— unnamed intermediate level —Group
  • 39.01.01.02PharmacoliteSpecies
CIM

20.2.8

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.8PharmacoliteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1800Selb (1800) Allgemeines Journal der Chemie, Berlin 1798-1803 (Scherer’s Journal): 4: 537 (as Arseniksaurer Kalk).
  2. 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 75 (as Pharmacolith).
  3. 1801Klaproth, M.H. (1801) Neueste analysen einiger fossilien. V. Chemische untersuchung der pharmacoliths. Allgemeines Journal der Chemie: 7: 67-71.
  4. 1802Klaproth, M. H. (1802) CVI. Untersuchung des Pharmakoliths. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.277-281.
  5. 1804Klaproth, M.H. (1804) Examination of pharmacolite. in Analytical Essays Towards Promoting the Chemical Knowledge of Mineral Substances. Volume 2, T. Cadell and W. Davies (London): 220-223.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pharmacolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pharmacolite-3184},
  note      = {Accessed 2026-05-11}
}