Where it forms, where it's found
- Geological setting
Found on oxidized arsenic ores; may be post-mining.
Oxidized zones of arsenical ore deposits.
- Type locality
- Sophia Mine
- Böckelsbach valley
- Wittichen
- Schenkenzell
- Rottweil
- Freiburg Region
- Baden-Württemberg
- Germany
48.3333°, 8.3333°
Safety & handling
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Lustre
- Vitreous · Silky
- Transparency
- Transparent · Translucent
- Colour
- White or colorless · grayish white · colorless in transmitted light.
- Streak
- White
- Tenacity
- brittle
- Cleavage
- Perfect
On (010), perfect.
- Fracture
- Irregular/Uneven
- Density
- 2.53 g/cm³
Optical
- Optical type
- Biaxial (-) · 2V measured = 77° · 2V calc = 84°
- Refractive index
- 1.58 – 1.594
- Surface relief
- Moderate
- Principal indices
- nα 1.580 – 1.583 · nβ 1.589 – 1.590 · nγ 1.590 – 1.594
- Birefringence
- 0.010
- Pleochroism
- Non-pleochroic
- Dispersion
- r > v
- Extinction
- Z=b; X ^ c = 29°
- UV response
- May be fluorescent pale blue in SW UV
Crystallography
- Cell parameters
- a = 5.9745 Å · b = 15.4340 Å · c = 6.2797 Å
- Cell angles
- β = 114.83 °
- Ratio a:b:c
- 1 : 2.583 : 1.051
- Z
- 4
- Morphology
Crystals tiny, rare, flattened on (010) or needle-like [001]. Silky fibrous; acicular clusters; botryoidal and stalactitic.
- Comment
Space group Ia (non-standard setting). If Z = 8, there is a similarity to krautite. Another setting is C-centered: a ~ 6.59, b ~ 15.43, c ~ 5.98 Å, β ~ 120.3°.
Chemical composition
Synonyms
- Arsenicit
- Arsenicita
- Arsenikbluethe
- Arsenikblüte
- Arseniksaurer Kalk
- Parmakit
- Pharmacoliet
- Pharmacolit
In other languages
- French
- pharmacolite
- German
- Pharmakolith
- Spanish
- farmacolita
- Italian
- farmacolite
- Portuguese
- farmacolite
- Chinese
- 毒石
- Russian
- фармаколит
Classification
8.CJ.50
- 8Phosphates, Arsenates, VanadatesClass
- 8.CPhosphates without additional anions, with H2ODivision
- 8.CJWith only large cationsGroup
- 8.CJ.50PharmacoliteSpecies
39.01.01.02
- 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
- 39.01A[HXO4]·xH2OType
- 39.01.01— unnamed intermediate level —Group
- 39.01.01.02PharmacoliteSpecies
20.2.8
- 20Arsenates (also arsenates with phosphate, but without other anions)Class
- 20.2Arsenates of Be, Mg, Ca or BaGroup
- 20.2.8PharmacoliteSpecies
Group, growth & confusion
Literature, links & citation
- 1800Selb (1800) Allgemeines Journal der Chemie, Berlin 1798-1803 (Scherer’s Journal): 4: 537 (as Arseniksaurer Kalk).
- 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 75 (as Pharmacolith).
- 1801Klaproth, M.H. (1801) Neueste analysen einiger fossilien. V. Chemische untersuchung der pharmacoliths. Allgemeines Journal der Chemie: 7: 67-71.
- 1802Klaproth, M. H. (1802) CVI. Untersuchung des Pharmakoliths. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.277-281.
- 1804Klaproth, M.H. (1804) Examination of pharmacolite. in Analytical Essays Towards Promoting the Chemical Knowledge of Mineral Substances. Volume 2, T. Cadell and W. Davies (London): 220-223.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Pharmacolite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/pharmacolite-3184},
note = {Accessed 2026-05-11}
}





