Childrenite

Fe2+Al(PO4)(OH)2 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Chd
Discovered
1823
Also known as
  • Childreniet

Where it forms, where it's found

Geological setting

Low temperature hydrothermal veins.

Complex granitic pegmatites, a low temperature hydrothermal alteration product of primary phosphates.

Type locality
Devon
  1. England
  2. UK
101recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellowish brown · brown · clove-brown

Colourless in transmitted light.

Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

Poor on (100)

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.11 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 40 – 45° · 2V calc = 50°
Refractive index
1.644 – 1.691
Surface relief
High
Principal indices
nα 1.644 – 1.649 · nβ 1.662 – 1.683 · nγ 1.671 – 1.691
Birefringence
0.035
Pleochroism
Visible

X= yellow Y= pink Z= pale pink to colourless

Dispersion
r > v strong
Extinction
X = a; Y = b; Z = c. In optically twined matrial Y ∧ c = 4°-8°.
UV response
Not Fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#20
Cell parameters
a = 10.41 Å · b = 13.42 Å · c = 6.92 Å
Cell angles
α = 90 ° · β = 90 ° · γ = 90 °
Ratio a:b:c
1 : 1.289 : 0.665
Morphology

Equant to pyramidal crystals, short prismatic [001], tabular, platy, radiating groups, fibrous crusts, massive.

Twinning

Common. May show on (100) and (001). Twins evident when of varying proportions but symmetrical twins consist of four to eight individuals in sectors with four individuals comprising a "termination". Visible twinning is uncommon.

Type-locality form

Small yellow crystals on quartz.

Comment

Bba2; possibly monoclinic pseudo-orthorhombic.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
48.73%
26FeIronIron155.84555.845
24.30%
15PPhosphorusPhosphorus130.97430.974
13.48%
13AlAluminiumAluminium126.98226.982
11.74%
1HHydrogenHydrogen41.0084.032
1.75%
Total229.826100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • Mn

Synonyms

  • Childreniet

In other languages

French
Childrénite
German
Childrenit
Spanish
Childrenita
Italian
Childrenite
Chinese
磷铝铁石
Russian
Чилдренит
Arabic
تشلدرنايت

Classification

Strunz
10th ed.

8.DD.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.DD.20ChildreniteSpecies
Dana
8th ed.

42.07.01.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.07(AB)2(XO4)Zq·xH2OType
  • 42.07.01Childrenite GroupGroup
  • 42.07.01.01ChildreniteSpecies
CIM

19.12.57

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.57ChildreniteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1823Brooke, H.J.A. (1823) On some undescribed minerals. Childrenite. The Quarterly Journal of Science, Literature, and the Arts: 16: 274-277.
  2. 1852Rammelsberg, K.F.A. (1852) On the chemical constitution of childrenite. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science: 4(23): 118-120.
  3. 1863Brush, G.J. (1863) On Childrenite from Hebron in Maine. American Journal of Science and Arts: 36(107): 257.
  4. 1873Church, A. H. (1873) New analyses of certain mineral arseniates and phosphates. Journal of the Chemical Society, 26. 101-111 doi:10.1039/js8732600101DOI: 10.1039/js8732600101
  5. 1913(1913) Atlas Der Krystallformen Vol. 2 - Text - Band II - Calaverit-Cyanochroit. Carl Winters Universitätsbuchhandlung, Heidelberg.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Childrenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/childrenite-1003},
  note      = {Accessed 2026-05-11}
}