Cookeite

(Al,Li)3Al2(Si,Al)4O10(OH)8
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ckt
Discovered
1866
Also known as
  • Cookeite (of Brush)

Where it forms, where it's found

Geological setting

Late stage mineralization in granite pegmatites, also in veins, or hydrothermally altered sedimentary rocks.

Late stage hydrothermal alteration product in pegmatites, hydrothermal veins.

Type locality
Mount Mica Quarry
  1. Paris
  2. Oxford County
  3. Maine
  4. USA

44.2694°, -70.4731°

193recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White · yellowish green · greenish · pink · brown · grey · rarely lilac

Colorless when pure.

Streak
White
Tenacity
flexible
Cleavage
Perfect

on (001)

Fracture
Micaceous
Density
2.58 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 35 – 60°
Refractive index
1.572 – 1.6
Surface relief
Moderate
Principal indices
nα 1.572 – 1.576 · nβ 1.579 – 1.584 · nγ 1.589 – 1.6
Birefringence
0.014
Pleochroism
Visible

X=Y= pale green to pink Z= colorless to pale yellow

Dispersion
r < v
UV response
May fluoresce creamy yellow SW
Michel-Lévy diagramhighlighted lineδ = 0.0140
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]140 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation140 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.14 Å · b = 8.9 Å · c = 14.15 Å
Cell angles
β = 97-98 °
Ratio a:b:c
1 : 1.732 : 2.753
Z
2
Morphology

Pseudohexagonal platy crystals usually in worm-like aggregates.

Twinning

Around [310], composition plane (001); frequently shows six sector twins by polarized light microscopy.

Type-locality form

Pearly and micaceous, somewhat resembling nacrite. In hemispherical aggregations or more rarely in distinct six-sided prisms, that are bent into a vermicular form like some varieties of chlorite.

Comment

Rarely triclinic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
42.85%
13AlAluminiumAluminium926.982242.838
36.13%
14SiSiliconSilicon428.085112.340
16.72%
3LiLithiumLithium36.94020.820
3.10%
1HHydrogenHydrogen81.0088.064
1.20%
Total672.044100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Mg
  • Ca
  • Na
  • K

Synonyms

  • Cookeite (of Brush)

In other languages

French
Cookéite
German
Cookeit
Italian
Cookeite
Chinese
锂绿泥石

Classification

Strunz
10th ed.

9.EC.55

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.55CookeiteSpecies
Dana
8th ed.

71.04.01.02

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.04Sheets of 6-membered rings interlayered 1:1, 2:1, and octahedraType
  • 71.04.01Chlorite group (Tri-Dioctahedral)Group
  • 71.04.01.02CookeiteSpecies
CIM

16.1.5

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.1Aluminosilicates of LiGroup
  • 16.1.5CookeiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1866Brush, G.J. (1866) On cookeite, a new mineral species. American Journal of Science and Arts, 91, 246-248.
  2. 1968Sahama, Th.G., Knorring, Oleg v., Lehtinen, Martti (1968) Cookeite from the Muiane pegmatite, Zambezia, Mozambique. Lithos, 1 (1) 12-19 doi:10.1016/s0024-4937(68)80031-3DOI: 10.1016/s0024-4937(68)80031-3
  3. 1970Cerny, P. (1970). Compositional variations in cookeite. The Canadian Mineralogist, 10(4), 636-647.
  4. 1971Černý, P, Povondra, P, Staněk, J (1971) Two cookeites from Czechoslovakia: A boron-rich variety and a IIb polytype. Lithos, 4 (1) 7-15 doi:10.1016/0024-4937(71)90111-3DOI: 10.1016/0024-4937(71)90111-3
  5. 1972Flehmig, W.; Menschel, G. (1972) Über die Lithiumgehalte und das Auftreten von Cookeit (Lithiumchlorit) in permischen Sandsteinen von Nordhessen. Contributions to Mineralogy and Petrology, 34 (3). 211-223 doi:10.1007/bf00373293DOI: 10.1007/bf00373293
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cookeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cookeite-1121},
  note      = {Accessed 2026-05-11}
}