Fluor-liddicoatite

Ca(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
IMA status
  • Approved
IMA symbol
Fld
Also known as
  • Fluor-liddicoatiet
  • IMA1976-041

Where it forms, where it's found

Type locality
Near Antsirabe
  1. Vakinankaratra
  2. Madagascar
12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789107.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light-brown · pink to red · green · blue · rarely white.
Streak
Light brown, white
Tenacity
brittle
Cleavage
Poor/Indistinct

Poor on (0001)

Fracture
Irregular/Uneven · Conchoidal
Density
3.02 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.621 – 1.637
Surface relief
Moderate
Principal indices
nω 1.637 · nε 1.621
Pleochroism
Strong
Notes

O= dark brown E= light brown

Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 15.875(3) Å · c = 7.126(2) Å
Z
3
Morphology

Stout prismatic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3015.999479.970
50.75%
13AlAluminiumAluminium726.982188.874
19.97%
14SiSiliconSilicon628.085168.510
17.81%
20CaCalciumCalcium140.07840.078
4.24%
5BBoronBoron310.81032.430
3.43%
9FFluorineFluorine118.99818.998
2.01%
3LiLithiumLithium26.94013.880
1.47%
1HHydrogenHydrogen31.0083.024
0.32%
Total945.764100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Fe
  • Ti
  • Mg
  • Na
  • H2O

Synonyms

  • Fluor-liddicoatiet
  • IMA1976-041

In other languages

French
Fluoro-liddicoatite
German
Fluor-Liddicoatit · IMA 1976-041 · Liddicoatit
Spanish
Liddicoatita
Italian
Fluor-liddicoatite · Liddicoatite

Classification

Strunz
10th ed.

9.CK.05

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CK[Si6O18]12- 6-membered single rings, with insular complex anionsGroup
  • 9.CK.05Fluor-liddicoatiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1977Dunn, Pete J., Appleman, Daniel E., Nelen, Joseph E. (1977) Liddicoatite, a new calcium end-member of the tourmaline group. American Mineralogist, 62 (11-12) 1121-1124
  2. 1981Nuber, B. and K. Schmetzer (1981): Strukturverfeinerung von Liddicoatit: Neues Jahrbuch für Mineralogie, Monatshefte, 1981, 215-219.
  3. 1996Grew, Edward S.; Anovitz, Lawrence M. - Eds. (1996) Boron - Mineralogy, Petrology and Geochemistry. Reviews in Mineralogy Vol. 33. Mineralogical Society of America p.862
  4. 1999Aurisicchio, Carlo, Demartin, Francesco, Ottolini, Luisa, Pezzotta, Federicο (1999) Homogeneous liddicoatite from Madagascar: a possible reference material? First EMPA, SIMS and SREF data. European Journal of Mineralogy, 11 (2) 237-242 doi:10.1127/ejm/11/2/0237DOI: 10.1127/ejm/11/2/0237
  5. 2006Ertl, A., Hughes, J. M., Prowatke, S., Ludwig, T., Prasad, P. S.R., Brandstatter, F., Korner, W., Schuster, R., Pertlik, F., Marschall, H. (2006) Tetrahedrally coordinated boron in tourmalines from the liddicoatite-elbaite series from Madagascar: Structure, chemistry, and infrared spectroscopic studies. American Mineralogist, 91 (11) 1847-1856 doi:10.2138/am.2006.2245 DOI: 10.2138/am.2006.2245
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fluor-liddicoatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fluor-liddicoatite-41296},
  note      = {Accessed 2026-05-11}
}