Gayite

NaMnFe5(PO4)4(OH)6 · 2H2O
IMA status
  • Approved
IMA symbol
Gy
IMA approved
2009
Also known as
  • Gayiet
  • IMA2008-056

Where it forms, where it's found

Geological setting

granitic pegmatite with triplite masses.

Type locality
Gigante pegmatite
  1. Candelaria District
  2. Cruz del Eje department
  3. Córdoba Province
  4. Argentina

-31.4086°, -64.7719°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Greenish black
Streak
olive green
Tenacity
brittle
Cleavage
Perfect

(100)

Fracture
Irregular/Uneven
Density
3.15 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60° · 2V calc = 62.1°
Refractive index
1.787 – 1.806
Surface relief
High
Principal indices
nα 1.787 · nβ 1.792 · nγ 1.806
Pleochroism
Strong

strong with X (bluish-green) >>Z (orange) > Y (yellow).

Dispersion
r < v
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 25.975(3) Å · b = 5.1766(4) Å · c = 13.929(11) Å
Cell angles
β = 111.293(2) °
Ratio a:b:c
1 : 0.199 : 0.536
Z
4
Parting
none
Type-locality form

Tabular crystals reach 130 µm on edge and are often grouped, sometimes as curved, worm-like aggregates up to about 1 mm long composed of clusters of subparallel crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
43.88%
26FeIronIron555.845279.225
31.91%
15PPhosphorusPhosphorus430.974123.896
14.16%
25MnManganeseManganese154.93854.938
6.28%
11NaSodiumSodium122.99022.990
2.62%
1HHydrogenHydrogen101.00810.080
1.15%
Total875.105100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gayiet
  • IMA2008-056

In other languages

German
Gayit · IMA 2008-056
Italian
gayite
Chinese
磷钠锰铁石

Classification

Strunz
10th ed.

8.DK.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.15GayiteSpecies
Dana
8th ed.

42.09.01.05

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.01Burangaite GroupGroup
  • 42.09.01.05GayiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2010Kampf, A. R., Colombo, F., del Tanago, J. G. (2010) Gayite, a new dufrenite-group mineral from the Gigante granitic pegmatite, Cordoba province, Argentina. American Mineralogist, 95 (2) 386-391 doi:10.2138/am.2010.3299 DOI: 10.2138/am.2010.3299
  2. 2021(2021) Gayite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gayite-39302},
  note      = {Accessed 2026-05-11}
}