Matioliite

NaMgAl5(PO4)4(OH)6 · 2H2O
IMA status
  • Approved
IMA symbol
Mti
IMA approved
2005
Also known as
  • IMA2005-011
  • Matioliiet
  • UM1995-21-PO:AlCaHMgNa

Where it forms, where it's found

Geological setting

Secondary hydrothermal mineralization in a granite pegmatite

Type locality
Gentil claim
  1. Mendes Pimentel
  2. Minas Gerais
  3. Brazil

-18.6894°, -41.4503°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Blue to colourless
Streak
White
Density
2.948 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 43° · 2V calc = 44°
Refractive index
1.597 – 1.627
Surface relief
Moderate
Principal indices
nα 1.597 · nβ 1.627 · nγ 1.627
Pleochroism
Visible

Y > X > Z, X = light blue to colorless, Y = blue, Z = colorless

Dispersion
r > v
UV response
non-fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 25.075 Å · b = 5.047 Å · c = 13.437 Å
Cell angles
β = 110.97 °
Ratio a:b:c
1 : 0.201 : 0.536
Unit cell volume
1587.9 ų
Z
4
Type-locality form

Prismatic to tabular crystals, up to 1 mm long

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
54.84%
13AlAluminiumAluminium526.982134.910
19.27%
15PPhosphorusPhosphorus430.974123.896
17.70%
12MgMagnesiumMagnesium124.30524.305
3.47%
11NaSodiumSodium122.99022.990
3.28%
1HHydrogenHydrogen101.00810.080
1.44%
Total700.157100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-011
  • Matioliiet
  • UM1995-21-PO:AlCaHMgNa

In other languages

French
Matioliite
German
IMA 2005-011 · Matioliit
Italian
matioliite

Classification

Strunz
10th ed.

8.DK.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.15MatioliiteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 2006Atencio, D., Coutinho, J. M.V., Mascarenhas, Y. P., Ellena, J. A. (2006) Matioliite, the Mg-analog of burangaite, from Gentil mine, Mendes Pimentel, Minas Gerais, Brazil, and other occurrences. American Mineralogist, 91 (11) 1932-1936 doi:10.2138/am.2006.2233 DOI: 10.2138/am.2006.2233
  2. 2022(2022) Matioliite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Matioliite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/matioliite-27412},
  note      = {Accessed 2026-05-11}
}