Natrodufrénite

NaFe3+Fe3+5(PO4)4O(OH)5(H2O)2
IMA status
  • Approved
IMA symbol
Ndf
IMA approved
1981
Also known as
  • IMA1981-033
  • Natrodufréniet

Where it forms, where it's found

Geological setting

Limonitic ore bed; formed by low temperature, supergene alteration.

Type locality
Pluherlin Castle
  1. Rochefort-en-Terre
  2. Vannes
  3. Morbihan
  4. Brittany
  5. France

47.7001°, -2.3395°

59recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Greenish brown
Streak
Green
Tenacity
brittle
Density
3.20 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.756 – 1.775
Surface relief
High
Principal indices
nα 1.756 · nγ 1.775
Pleochroism
Visible

X = pale yellow; Z = dark green.

Dispersion
distinct to strong
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 25.83(2) Å · b = 5.150(3) Å · c = 13.772(9) Å
Cell angles
β = 111.53 °
Ratio a:b:c
1 : 0.199 : 0.533
Z
4
Morphology

Radially fibrous spherulites, to 5 mm, may be in warty nodules.

Type-locality form

Blue-green spheres of compact radiating fibers up to 0.5 cm in diameter.

Comment

By analogy to dufrénite.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
43.88%
26FeIronIron655.845335.070
38.29%
15PPhosphorusPhosphorus430.974123.896
14.16%
11NaSodiumSodium122.99022.990
2.63%
1HHydrogenHydrogen91.0089.072
1.04%
Total875.004100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1981-033
  • Natrodufréniet

In other languages

German
IMA 1981-033 · Natrodufrénit
Spanish
Natrodufrénita
Italian
Natrodufrénite

Classification

Strunz
10th ed.

8.DK.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.15NatrodufréniteSpecies
Dana
8th ed.

42.09.01.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.01Burangaite GroupGroup
  • 42.09.01.03NatrodufréniteSpecies
CIM

19.14.6

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.6NatrodufréniteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1982Fontan, François, Pillard, François, Permingeat, François (1982) La natrodufrénite (Na, ⃞)(Fe+++, Fe++)(Fe+++, Al) 5 (PO4) 4 (OH) 6• 2H2O, une nouvelle espèce minérale du groupe de la dufrénite. Bulletin de Minéralogie, 105 (4). 321-326 doi:10.3406/bulmi.1982.7623DOI: 10.3406/bulmi.1982.7623
  2. 1983Dunn, P.J.; Grice, J.D.; Fleischer, M.; Pabst, A. (1983) New mineral names. American Mineralogist, 68 (9-10). 1038-1041
  3. 1998Roda-Robles, Encarnación, Fontan, François, Pesquera Pérez, Alfonso, Keller, Paul (1998) The Fe-Mn phosphate associations from the Pinilla de Fermoselle pegmatite, Zamora, Spain: occurrence of kryzhanovskite and natrodufrénite. European Journal of Mineralogy, 10 (1) 155-168 doi:10.1127/ejm/10/1/0155DOI: 10.1127/ejm/10/1/0155
  4. 2005(2005) Natrodufrénite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2026Bosi, Ferdinando; Hatert, Frédéric; Pasero, Marco; Mills, Stuart J. (2026) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 89. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2026.10199DOI: 10.1180/mgm.2026.10199
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrodufrénite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrodufrenite-2854},
  note      = {Accessed 2026-05-11}
}