Where it forms, where it's found
- Geological setting
Iron ore deposit
Gossan of veins and in iron ore deposits; in iron-rich gossans; rarely in late-stage phosphate mineralization in granite pegmatites.
- Type locality
- Angelard
- Compreignac
- Bellac
- Haute-Vienne
- Nouvelle-Aquitaine
- France
45.9746°, 1.3109°
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Lustre
- Vitreous · Silky
- Transparency
- Translucent · Opaque
- Colour
- Dark green · olive-green · olive-brown · black · olive-brown to reddish brown with oxidation · bluish green to reddish brown or yellow in transmitted light.
- Streak
- Green
- Tenacity
- brittle
- Cleavage
- Perfect
One perfect, a second cleavage good and both parallel to the fibre direction, with traces of a poor third cleavage at right angles to the other two.
- Fracture
- Fibrous
- Density
- 3.1 g/cm³
Optical
- Optical type
- Biaxial (+/-) · 2V measured = 90° · 2V calc = 38 – 52°
- Refractive index
- 1.82 – 1.925
- Surface relief
- Very high
- Principal indices
- nα 1.82 – 1.842 · nβ 1.83 – 1.85 · nγ 1.875 – 1.925
- Birefringence
- 0.055
- Pleochroism
- Visible
X = Deep blue, light brown, light yellow-brown or deep bluish green Y = Buff, brown, light brown, light yellow-brown Z = Deep red-brown, dark brown, red-brown, deep olive-brown (from localities: Rock Run, AL; Siegen, Westphalia; Wheal Phoenix; and Hirs
- Dispersion
- r<v relatively strong; also r >v relatively strong
- UV response
- Not Fluorescent in UV
Crystallography
- Space group
- C2/c
- Cell parameters
- a = 25.84(2) Å · b = 5.126(3) Å · c = 13.78(1) Å
- Cell angles
- β = 111.20(6) °
- Ratio a:b:c
- 1 : 0.198 : 0.533
- Z
- 2
- Morphology
Crystals rare, indistinct, in subparallel or sheaf-like aggregates. Botryoidal masses or crusts with a radial-fibrous structure, common. The crusts are formed of drusy crystals with rounded or exfoliated terminations at times.
- Comment
SG C2/c
Chemical composition
Synonyms
- Alluadite (of Bernhardi)
- Dufréniet
- Fer oxidé, terreaux, jaune verdâtre
- Grüneisenerde
- Grüneisenerz
- Grüneisenstein, strahlicher, ochricher
- Kraurit
- Kraurite
- Strahlstein (of Jordan)
In other languages
- French
- dufrénite
- German
- Dufrénit
- Spanish
- dufrénita
- Italian
- dufrénite
Classification
8.DK.15
- 8Phosphates, Arsenates, VanadatesClass
- 8.DPhosphates, etc. with additional anions, with H2ODivision
- 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
- 8.DK.15DufréniteSpecies
42.09.01.02
- 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
- 42.09(AB)7(XO4)4Zq·xH2OType
- 42.09.01Burangaite GroupGroup
- 42.09.01.02DufréniteSpecies
19.13.4
- 19PhosphatesClass
- 19.13Phosphates of Fe aloneGroup
- 19.13.4DufréniteSpecies
Group, growth & confusion
BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMineral—
CacoxeniteFe3+24AlO6(PO4)17(OH)12 · 75H2OMineral—
ChalcosideriteCuFe3+6(PO4)4(OH)8 · 4H2OMineral—
Churchite-(Y)Y(PO4) · 2H2OMineral—
GoethiteFeO(OH)Mineral—
MatulaiteFe3+Al7(PO4)4(PO3OH)2(OH)8(H2O)8 · 8H2OMineral—
SideriteFe(CO3)Mineral—
StrengiteFe3+(PO4) · 2H2OMineral—
Literature, links & citation
- 1803Jordan (1803) Min. Reisebem.: 243 (as Strahlstein).
- 1814Ullmann, J.C. (1814) Systematisch-Tabellarische Uebersicht der min.-einfachen Fossilien. Cassel and Marburg: 152. (as Grüneisenstein, strahlicher, ochrichter)
- 1822Haüy, René Just (1822) Traité de Minéralogie (2nd ed.) Vol. 4. Bachelier, Paris.
- 1833Brongniart, A. (1833) Dufrénite. in Tableau de la distribution méthodique des espèces minérales suivie dans le cours de minèralogie fait au Musèum Royal d'Histoire Naturelle en 1833, A la Librairie Encyclopèdique de Roret (Paris), 48pp., 8vo: 20.
- 1841Breithaupt, A. (1841) Vollständige Handbuch der Mineralogie: 2: 152. (as Kraurit)
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Dufrénite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/dufrenite-1323},
note = {Accessed 2026-05-11}
}



