Dufrénite

Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dfr
Discovered
1833
Also known as
  • Alluadite (of Bernhardi)
  • Dufréniet
  • Fer oxidé, terreaux, jaune verdâtre
  • +6 more

Where it forms, where it's found

Geological setting

Iron ore deposit

Gossan of veins and in iron ore deposits; in iron-rich gossans; rarely in late-stage phosphate mineralization in granite pegmatites.

Type locality
Angelard
  1. Compreignac
  2. Bellac
  3. Haute-Vienne
  4. Nouvelle-Aquitaine
  5. France

45.9746°, 1.3109°

130recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Silky
Transparency
Translucent · Opaque
Colour
Dark green · olive-green · olive-brown · black · olive-brown to reddish brown with oxidation · bluish green to reddish brown or yellow in transmitted light.
Streak
Green
Tenacity
brittle
Cleavage
Perfect

One perfect, a second cleavage good and both parallel to the fibre direction, with traces of a poor third cleavage at right angles to the other two.

Fracture
Fibrous
Density
3.1 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 90° · 2V calc = 38 – 52°
Refractive index
1.82 – 1.925
Surface relief
Very high
Principal indices
nα 1.82 – 1.842 · nβ 1.83 – 1.85 · nγ 1.875 – 1.925
Birefringence
0.055
Pleochroism
Visible

X = Deep blue, light brown, light yellow-brown or deep bluish green Y = Buff, brown, light brown, light yellow-brown Z = Deep red-brown, dark brown, red-brown, deep olive-brown (from localities: Rock Run, AL; Siegen, Westphalia; Wheal Phoenix; and Hirs

Dispersion
r<v relatively strong; also r >v relatively strong
UV response
Not Fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0550
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]550 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation550 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 25.84(2) Å · b = 5.126(3) Å · c = 13.78(1) Å
Cell angles
β = 111.20(6) °
Ratio a:b:c
1 : 0.198 : 0.533
Z
2
Morphology

Crystals rare, indistinct, in subparallel or sheaf-like aggregates. Botryoidal masses or crusts with a radial-fibrous structure, common. The crusts are formed of drusy crystals with rounded or exfoliated terminations at times.

Comment

SG C2/c

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
43.98%
26FeIronIron655.845335.070
38.38%
15PPhosphorusPhosphorus430.974123.896
14.19%
20CaCalciumCalcium0.540.07820.039
2.30%
1HHydrogenHydrogen101.00810.080
1.15%
Total873.061100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Alluadite (of Bernhardi)
  • Dufréniet
  • Fer oxidé, terreaux, jaune verdâtre
  • Grüneisenerde
  • Grüneisenerz
  • Grüneisenstein, strahlicher, ochricher
  • Kraurit
  • Kraurite
  • Strahlstein (of Jordan)

In other languages

French
dufrénite
German
Dufrénit
Spanish
dufrénita
Italian
dufrénite

Classification

Strunz
10th ed.

8.DK.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.15DufréniteSpecies
Dana
8th ed.

42.09.01.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.01Burangaite GroupGroup
  • 42.09.01.02DufréniteSpecies
CIM

19.13.4

  • 19PhosphatesClass
  • 19.13Phosphates of Fe aloneGroup
  • 19.13.4DufréniteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1803Jordan (1803) Min. Reisebem.: 243 (as Strahlstein).
  2. 1814Ullmann, J.C. (1814) Systematisch-Tabellarische Uebersicht der min.-einfachen Fossilien. Cassel and Marburg: 152. (as Grüneisenstein, strahlicher, ochrichter)
  3. 1822Haüy, René Just (1822) Traité de Minéralogie (2nd ed.) Vol. 4. Bachelier, Paris.
  4. 1833Brongniart, A. (1833) Dufrénite. in Tableau de la distribution méthodique des espèces minérales suivie dans le cours de minèralogie fait au Musèum Royal d'Histoire Naturelle en 1833, A la Librairie Encyclopèdique de Roret (Paris), 48pp., 8vo: 20.
  5. 1841Breithaupt, A. (1841) Vollständige Handbuch der Mineralogie: 2: 152. (as Kraurit)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dufrénite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dufrenite-1323},
  note      = {Accessed 2026-05-11}
}