Groatite

◻NaCaMn2(PO4)(HPO4)2
IMA status
  • Approved
IMA symbol
Goa
IMA approved
2008
Also known as
  • Groatiet
  • IMA2008-054

Where it forms, where it's found

Geological setting

In a vug in a single 5–10 cm mass of phosphate–carbonate mineralization in a spodumene-rich boulder.

Type locality
Tanco Mine
  1. Bernic Lake
  2. Lac-du-Bonnet area
  3. Manitoba
  4. Canada

50.4300°, -95.4464°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colourless to pale yellow

Pale orange, where massive

Streak
White
Tenacity
brittle
Cleavage
None Observed

Crystals are too small in cross-section to observe cleavage.

Fracture
Irregular/Uneven
Density
3.213 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 67° · 2V calc = 66.5°
Refractive index
1.622 – 1.663
Surface relief
Moderate
Principal indices
nα 1.622 · nβ 1.634 · nγ 1.663
Birefringence
0.041
Pleochroism
Non-pleochroic
Extinction
X ∧ a = 35.4 (in β obtuse); Y ∧ c = 10.1° (in β acute); Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.0410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]410 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation410 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C1 2/c 1
Cell parameters
a = 12.5435(9) Å · b = 12.4324(9) Å · c = 6.7121(4) Å
Cell angles
β = 115.332(2) °
Ratio a:b:c
1 : 0.991 : 0.535
Unit cell volume
946.07 ų
Z
4
Twinning

None observed.

Parting
None observed.
Type-locality form

Slightly divergent sprays of acicular crystals on whitlockite; stellate sprays embedded in whitlockite and an unidentified Na–Al phosphate; tabular mass of densely intergrown acicular crystals.

Crystal structure

Chemical composition

Impurities
  • Fe

Synonyms

  • Groatiet
  • IMA2008-054

In other languages

German
Groatit · IMA 2008-054
Italian
groatite
Chinese
磷钠钙锰石

Classification

Strunz
10th ed.

8.AC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.10GroatiteSpecies
Dana
8th ed.

39.02.07.06

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.07Lindackerite GroupGroup
  • 39.02.07.06GroatiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2009Cooper, Mark A., Hawthorne, Frank C., Ball, Neil A., Ramik, Robert A., Roberts, Andrew C. (2009) Groatite, NaCaMn2+2(PO4)[PO3(OH)]2, a new mineral species of the alluaudite group from the Tanco Pegmatite, Bernic Lake, Manitoba, Canada: description and crystal structure. The Canadian Mineralogist, 47 (5) 1225-1235 doi:10.3749/canmin.47.5.1225 DOI: 10.3749/canmin.47.5.1225
  2. 2011(2011) Groatite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Groatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/groatite-39288},
  note      = {Accessed 2026-05-11}
}