Hagendorfite

Na2MnFe2+Fe3+(PO4)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hag
Discovered
1954
Also known as
  • Arrojadite (of Mason)
  • Hagendorfiet

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Hagendorf South Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6503°, 12.4597°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Black to greenish-black
Tenacity
brittle
Cleavage
Distinct/Good

(010) good; two other cleavages poor.

Fracture
Irregular/Uneven
Density
3.71 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 68 – 70° · 2V calc = 66°
Refractive index
1.708 – 1.745
Surface relief
High
Principal indices
nα 1.708 – 1.735 · nβ 1.742 · nγ 1.722 – 1.745
Birefringence
0.012
Pleochroism
Visible
Dispersion
r > v
UV response
Not fluorescent.
Notes

X=tan to yellowish green, Z=blue green to grass green.

Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 11.9721 Å · b = 12.5988 Å · c = 6.5029 Å
Cell angles
β = 114.841 °
Ratio a:b:c
1 : 1.052 : 0.543
Z
4
Morphology

Abstract: The crystal structure of hagendorfite (Na,Ca)MnFe2(PO4)3 from type locality has been determined and it was found to be isostructural with alluaudite. It accepts space group symmetry C2/c both at room temperature and at 100 K. The specific arrangement of M(1) and M(2) octahedral sites and of P(1) and P(2) tetrahedral sites gives rise to two different channels aligned along the crystallographic c-axis, containing the A(1) and A(2)' sites. The A(1) site is fully occupied and shows a mixed occupation of Na+, Ca2+ and Mn2+ (hagendorfite). The A(2)' is fully occupied by Na+ in hagendorfite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
38.59%
26FeIronIron255.845111.690
22.45%
15PPhosphorusPhosphorus330.97492.922
18.68%
25MnManganeseManganese154.93854.938
11.04%
11NaSodiumSodium222.99045.980
9.24%
Total497.518100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadite (of Mason)
  • Hagendorfiet

In other languages

German
Hagendorfit

Classification

Strunz
10th ed.

8.AC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.10HagendorfiteSpecies
Dana
8th ed.

38.02.03.02

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.03Alluaudite-Wyllieite Group (Alluaudite Subgroup)Group
  • 38.02.03.02HagendorfiteSpecies
CIM

19.12.48

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.48HagendorfiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1942Mason, Brian (1942) Some iron-manganese phosphate minerals from the pegmatite at Hühnerkobel in Bavaria. Geologiska Föreningen i Stockholm Förhandlingar, 64 (3) 335-340 doi:10.1080/11035894209446083DOI: 10.1080/11035894209446083
  2. 1946Eriksson, T. (1946) Triphylite and arrojadite from Norro muscovite pegmatite. Arkiv för Kemi, Mineralogi och Geologi, Stockholm: 23A, no. 8.
  3. 1950Lindberg, Marie Louise (1950) Arrojadite, hühnerkobelite, and graftonite. American Mineralogist, 35 (1-2) 59-76
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1954Strunz, H. (1954) Hagendorfit, ein neues mineral der Varulith-Hühnerkobelit-Reihe. Neues Jahrbuch für Mineralogie, Monatshefte: 1954: 252-255.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hagendorfite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hagendorfite-1795},
  note      = {Accessed 2026-05-11}
}