Hydrozincite

Zn5(CO3)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hznc
Discovered
1853
Also known as
  • Cegamit
  • Cegamite
  • Earthy Calamine
  • +9 more

History

For most of mining history, hydrozincite had no name of its own. It hid inside calamine — the old catch-all term for the non-sulfide zinc ores that miners dug and smelters prized. Calamine was never one mineral. It was a jumble of zinc carbonates and zinc silicates lumped together because they looked alike and yielded the same metal. Until the 18th century, this mixed ore was the only practical route to brass, made by heating copper and calamine together in what was called the cementation process.

The tangle began to unravel in 1803. The British chemist James Smithson showed that what had passed for one ore was really two distinct minerals — a zinc carbonate and a zinc silicate. Those two were later named smithsonite and hemimorphite. Hydrozincite, another zinc carbonate within the calamine family, was still waiting for its own description.

That came in 1853. The German mineralogist Gustav Adolph Kenngott described the mineral from an occurrence at Bad Bleiberg in Carinthia, Austria. He named it for its make-up — water of hydration bound together with zinc. The same year, Kenngott also gave hemimorphite its modern name, helping close the long confusion that calamine had created.

Collectors and miners knew hydrozincite by plainer names too. Its habit of forming pale crusts on weathering zinc ores earned it the nickname zinc bloom, and it has also gone by marionite.

Industrial & practical applications

Hydrozincite is a minor ore of zinc. It is never the metal's main source — that role belongs to sphalerite, the zinc sulfide that supplies almost all mined zinc. Where hydrozincite does count is in the weathered upper parts of zinc deposits, the oxidised caps that sit above the sulfide ore. There it forms alongside other non-sulfide zinc minerals and adds to what can be recovered, rather than standing on its own.

Its most reliable use is as a marker in the field and the cabinet. Under ultraviolet light, hydrozincite glows pale blue to lilac. Geologists read that glow as a sign of zinc in a rock, and collectors prize the same fluorescence in display specimens.

A newer, more unexpected role is environmental. The Rio Naracauli is a stream in Sardinia draining old zinc workings. There, hydrozincite precipitates through a process driven by living microbes — a microalga and a cyanobacterium. The mineral locks up roughly 1.2 kilograms of zinc per day, removing close to 90 percent of the metal carried by the water. That capacity has prompted researchers to propose this biomineralization as a way to clean zinc out of mine drainage where the water is near neutral in acidity.

Where it forms, where it's found

Geological setting

Oxidized zones of zinc mineral deposits, particularly those with sphalerite.

Type locality
Bad Bleiberg
  1. Villach-Land District
  2. Carinthia
  3. Austria

46.6167°, 13.6833°

1,040recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White to grey · stained pale pink · or pale yellow or brown · colourless in transmitted light.
Streak
White
Tenacity
very brittle
Cleavage
Perfect

On (100).

Fracture
Irregular/Uneven
Density
3.5 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 40° · 2V calc = 40°
Refractive index
1.63 – 1.75
Surface relief
High
Principal indices
nα 1.63 · nβ 1.642 · nγ 1.75
Dispersion
relatively strong
UV response
Light blue (SW UV). May fluoresce weak gray, white, or pale yellow in mid-wave and long wave. Probably does not phosphorece except due to mixture with other species. blue shortwave-excited luminescence excited by SW UV caused by titanate groups (TiO<sub>6</sub>)
Michel-Lévy diagramhighlighted lineδ = 0.1200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1200 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1200 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C1 2/m 1
Cell parameters
a = 13.58 Å · b = 6.28 Å · c = 5.41 Å
Cell angles
β = 95.51 °
Ratio a:b:c
1 : 0.462 : 0.398
Z
2
Morphology

Crystals usually very small to microscopic, lath-like or bladed, flattened on (100) and elongated [001], often tapering to a sharp point. Typically found as massive aggregates of either powdery material, earthy and porous, to compact material, with fibrous radial structure, may be reniform. Dense agate-like masses, stalactic, and pisolitic.

Twinning

Intimate twinning has been observed, but the morphology has not been reported.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc565.380326.900
59.55%
8OOxygenOxygen1215.999191.988
34.97%
6CCarbonCarbon212.01124.022
4.38%
1HHydrogenHydrogen61.0086.048
1.10%
Total548.958100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Cu

Synonyms

  • Cegamit
  • Cegamite
  • Earthy Calamine
  • Hydro-carbonate of zinc
  • Idrozincit
  • Marionit
  • Marionite
  • Zinc Bloom
  • Zinconine
  • Zinconise
  • Zinkblüte
  • Zinkblüthe

In other languages

French
hydrozincite · Zinconise
German
Hydrozinkit · Zinkblüte
Spanish
Flor de cinc · hidrocincita
Italian
Fiore di zinco · idrozincite
Japanese
水亜鉛土
Chinese
水锌矿
Russian
гидроцинкит
Arabic
هيدروزنسيت · هيدروزنكيت

Classification

Strunz
10th ed.

5.BA.15

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BAWith Cu, Co, Ni, Zn, Mg, MnGroup
  • 5.BA.15HydrozinciteSpecies
Dana
8th ed.

16a.04.01.01

  • 16aAnhydrous Carbonates Containing Hydroxyl or HalogenClass
  • 16a.04(AB)5(XO3)2ZqType
  • 16a.04.01— unnamed intermediate level —Group
  • 16a.04.01.01HydrozinciteSpecies
CIM

11.6.2

  • 11CarbonatesClass
  • 11.6Carbonates of Zn and CdGroup
  • 11.6.2HydrozinciteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1803Smithson, J. (1803) A chemical analysis of some calamines. Royal Society of London, Philosophical Transactions: 12-28. (as Calamine)
  2. 1808Karsten, D.L.G. (1808) Mineralogische Tabellen, Berlin, second edition: 70, 99 (as Zinkblüthe).
  3. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  4. 1853Kenngott, G.A. (1853) Ubersichte der Resultate mineralogischer Forschungen, for the years 1850-51, Vienna (as Hydrozinkit).
  5. 1858Elderhorst (1858) Geological Report of Arkansas: 153. (as Marionite).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydrozincite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydrozincite-1993},
  note      = {Accessed 2026-05-11}
}