Hemimorphite

Zn4(Si2O7)(OH)2 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hmp
Discovered
1853
Also known as

History

For most of mineralogy's history, hemimorphite did not have its own name. It hid inside an older word: calamine.

Calamine came from the Latin lapis calaminaris, itself a corruption of the Greek kadmia — the ancient catch-all term for zinc ores. Miners and metalworkers had used the word for centuries to describe the pale, often botryoidal masses they smelted for zinc and brass. The trouble was that two different minerals answered to the name. Both formed in the weathered upper levels of zinc deposits. Both looked, in hand specimen, much the same. One worked beautifully as a zinc ore. The other did not.

The puzzle was settled in 1803, when the British chemist and mineralogist James Smithson took the question into the laboratory. He showed that calamine was in fact a mixture of two distinct compounds — a zinc carbonate, which yielded zinc readily, and a zinc silicate, which did not. The carbonate would later be named smithsonite in his honour, after his death in 1829.

The silicate — what we now call hemimorphite — kept the old calamine name for another fifty years.

It received its modern name in 1853, from the mineralogist Adolph Kenngott. He coined hemimorphite from the Greek hēmi (half) and morphē (form), in reference to a quirk of the mineral's crystal symmetry. The crystals are hemimorphic — meaning the two ends of a crystal develop differently, one terminated by a blunt face, the other by a sharp pyramid. Only a handful of mineral species do this, and the asymmetry is the species' defining structural feature.

For more than a century after Kenngott's paper, English and European literature kept using calamine and hemimorphite interchangeably. The International Mineralogical Association finally settled the matter in 1962, formally choosing hemimorphite over calamine as the species name. Calamine survives today only in pharmacy — the pink calamine lotion sold for skin irritations is a mixture of zinc oxide and iron oxide.

Industrial & practical applications

Hemimorphite is, first and foremost, a secondary ore of zinc — a supplemental source, not a primary one. Roughly half its weight is zinc; published figures put the metal content at up to 54%. The mineral forms where primary zinc sulfide ore — chiefly sphalerite (ZnS) — has been weathered or chemically altered near the surface. That alteration leaves a band of oxidised zinc minerals capping the unweathered sulfide body below. Most modern zinc comes from sphalerite at depth; hemimorphite is mined where the oxidised upper layer is rich enough to recover.

The other practical use is lapidary. The blue-to-blue-green botryoidal variety — bunched, grape-cluster aggregates with a milky pastel colour reminiscent of turquoise — is cut into cabochons, beads, pendants, and earrings. The best of this material has come from the Wenshan Mine in Yunnan, China, and from the Ojuela Mine in Durango, Mexico. Working it is delicate. The mineral has perfect cleavage and a Mohs hardness of only 4½ to 5. Jewellers therefore reserve it for pieces that will not see hard knocks — pendants and earrings, rarely rings.

Beyond zinc recovery and ornament, the mineral has no significant industrial role. It is sought by collectors for well-formed transparent crystals and for the blue botryoidal pieces, and otherwise lives in the secondary literature on oxidised zinc deposits.

Where it forms, where it's found

Geological setting

Secondary mineral in the weathered portions of zinc deposits.

Type locality
Băiţa mining district
  1. Nucet
  2. Bihor County
  3. Romania

46.4818°, 22.5806°

1,669recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · white · pale blue · pale green · gray · brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (110), poor on (101), (001) rare

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.475 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 46° · 2V calc = 44°
Refractive index
1.614 – 1.636
Surface relief
Moderate
Principal indices
nα 1.614 · nβ 1.617 · nγ 1.636
Birefringence
0.022
Dispersion
strong r > v
Extinction
X = b; Y = a; Z = c.
UV response
May be bluish under SW UV.
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Imm2
Cell parameters
a = 8.367(5) Å · b = 10.730 Å · c = 5.155(3) Å
Ratio a:b:c
1 : 1.282 : 0.616
Z
2
Morphology

Thin tabular crystals, sheaf-like or fan-like aggregates, stalactitic, mammillary, botryoidal.

Twinning

On (101) rare

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc465.380261.520
54.29%
8OOxygenOxygen1015.999159.990
33.21%
14SiSiliconSilicon228.08556.170
11.66%
1HHydrogenHydrogen41.0084.032
0.84%
Total481.712100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • Fe

Synonyms

  • Calamina
  • Daviesit
  • Daviesita
  • Electric Calamine
  • Gemeiner Galmei
  • Hemimorphita
  • Kieselgalmei
  • Kieselgalmey
  • Kieselzinkerz
  • Kieselzinkspat
  • Smithsonite (of Brooke and Miller)
  • Wagit
  • Wagita
  • Wagite
  • Zinkglas
  • Zinkkieselerz

In other languages

French
E557 · hémimorphite · Oxyde de zinc silicifère · Silicate de zinc · Wagite · Zinc oxydé silicifère
German
Hemimorphit · Kieselzinkerz
Spanish
hemimorfita
Italian
emimorfite
Portuguese
hemimorfita · Hemimorfite
Japanese
ヘミモルファイト · 異極鉱
Chinese
异极矿 · 異極礦
Traditional Chinese
異極礦
Russian
Гемиморфит · Каламин
Arabic
هيميمورفيت

Classification

Strunz
10th ed.

9.BD.10

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BDSi2O7 groups, with additional anions; cations in tetrahedral [4] and greater coordinationGroup
  • 9.BD.10HemimorphiteSpecies
Dana
8th ed.

56.01.02.01

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.01Si2O7 Groups and O, OH, F, and H2O with cations in [4] coordinationType
  • 56.01.02— unnamed intermediate level —Group
  • 56.01.02.01HemimorphiteSpecies
CIM

14.7.12

  • 14Silicates not Containing AluminumClass
  • 14.7Silicates of Ba, Sr and ZnGroup
  • 14.7.12HemimorphiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1853Kenngott, A. (1853) Hemimorphit. in Das Mohs’sche Mineralsystem, Verlag und Druck (Wien): 67-68.
  2. 1884Thomson, J. Stuart (1884) Note on Crystals of Calamine from Wanlockhead, Dumfries-shire. Mineralogical Magazine and Journal of the Mineralogical Society, 5 (26) 332 doi:10.1180/minmag.1884.005.26.04 DOI: 10.1180/minmag.1884.005.26.04
  3. 1894Pratt, J.H. (1894) Mineralogical Notes on Cerussite, Calamine and Zircon. American Journal of Science: 48(285): 212.
  4. 1899Clarke, F.W., Steiger, G. (1899) Experiments relative to the Constitution of Pectolite, Pyrophyllite, Calamine, and Analcite. American Journal of Science: 8(46): 245.
  5. 1911Pogue, J.E. (1911) On calamine crystals from Mexico, rutile-mica intergrowths from Canada, and pseudomorphs of marcasite arfter pyrrhotite from Russia. Proceedings U.S. National Museum: 39(1801): 571-579.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hemimorphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hemimorphite-1860},
  note      = {Accessed 2026-05-11}
}