Ilvaite

CaFe3+Fe2+2O(Si2O7)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ilv
Discovered
1784
Also known as
  • Baddeleyite (of Clarke)
  • Breislakit
  • Breislakita
  • +8 more

Where it forms, where it's found

Geological setting

Contact metasomatic rocks and iron deposits.

Type locality
Torre di Rio - Santa Filomena area (Monte della Torre)
  1. Rio Marina
  2. Rio
  3. Livorno Province
  4. Tuscany
  5. Italy

42.8136°, 10.4295°

207recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Iron-black · dark grayish black
Streak
Black, inclining to green or brown
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (001) (010)

Fracture
Irregular/Uneven
Density
3.99 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 20 – 30° · 2V calc = 30°
Refractive index
1.727 – 1.883
Surface relief
Very high
Principal indices
nα 1.727 · nβ 1.87 · nγ 1.883
Pleochroism
Strong

X= dark green Y= yellow-brown to dark brown Z= dark brown

Dispersion
Strong r<v
Extinction
X > Y > Z
Optical colour
light gray to bluish gray, pinkish red to violet
Anisotropism
Very strong
Tropism
Anisotropic
Reflectance R%
(8.7,10.4) 400, (8.6,10.3) 420, (8.5,10.2) 440, (8.2,10.1) 460, (7.9,10.0) 480, (7.6,9.9) 500, (7.3,9.8) 520, (7.0,9.8) 540, (6.7,9.8) 560, (6.3,9.8) 580, (5.8,9.8) 600, (5.5,9.8) 620, (5.2,9.8) 640, (5.0,9.8) 660, (5.1,9.7) 680, (5.4,9.6) 700
Notes

X=c, Y=b, Z=a

Reflected-light panel
6.8 %anisotropic · dual curve
Specimen sRGB 90, 69, 40
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Very strong
Reflected colour
light gray to bluish gray, pinkish red to violet

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 8.800 Å · b = 13.019 Å · c = 5.852 Å
Ratio a:b:c
1 : 1.479 : 0.665
Z
4
Morphology

Prismatic, columnar, radiating, compact massive,

Type-locality form

A sample collected in 1801 by Claude-Hugues Leliévre measuring 17 x 14 cm with about 50 shiny crystals.

Comment

Orthorhombic (Pbnm; cell parameters given refer to this space-group symmetry) or monoclinic (P21/a; 13.0103(5), 8.8039(4), 5.8517(3), 90.209(5))

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron355.845167.535
40.98%
8OOxygenOxygen915.999143.991
35.23%
14SiSiliconSilicon228.08556.170
13.74%
20CaCalciumCalcium140.07840.078
9.80%
1HHydrogenHydrogen11.0081.008
0.25%
Total408.782100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Mn

Synonyms

  • Baddeleyite (of Clarke)
  • Breislakit
  • Breislakita
  • Cyclopeita
  • Elbaite (of Giesecke)
  • Lievrit
  • Lievrita
  • Lievrite
  • Yenit
  • Yenita
  • Yenite

In other languages

French
ilvaïte
German
Ilvait · Jenit · Lievrit · Yenit
Spanish
Ilvaíta
Italian
Ilvaite · lievrite, yenite, breislaite
Japanese
珪灰鉄鉱
Chinese
黑柱石
Russian
Ильваит

Classification

Strunz
10th ed.

9.BE.07

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.07IlvaiteSpecies
Dana
8th ed.

56.02.03.03

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.03Lawsonite - Ilvaite groupGroup
  • 56.02.03.03IlvaiteSpecies
CIM

14.22.7

  • 14Silicates not Containing AluminumClass
  • 14.22Silicates of Fe and CaGroup
  • 14.22.7IlvaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1807Lelièvre, C.H. (1807) De la yénite, nouvelle substance minérale. Journal des Mines, 21, 65-74. [As yenite] http://annales.ensmp.fr/articles/1807-1/33-39.pdf
  2. 1807D'Aubuisson, Jean-François (1807) Nachricht über ein neues Mineral, Jenit genannt. Journal für die Chemie und Physik, 3, 1, 86-87
  3. 1808Thiébaut de Berneaud, Arsenne (1808) Voyage à l'isle d'Elbe, suivi d'une notice sur les autres isles de la mer Tyrrhénienne. D. Colas & Le Normant, Paris, xvi+231 pp. https://books.google.it/books?id=tDB-8bB03vsC&printsec=f
  4. 1811Steffens, H. (1811) Ilvait. in Vollständiges Handbuch der Oryktognosie, Erster Theil (Halle, Germany): 356-358.
  5. 1812Hoffmann, C.A. s. (1812) Handbuch der Mineralogie II, Freiberg, Verl. Craz & Gerlach,p. 376.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ilvaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ilvaite-2016},
  note      = {Accessed 2026-05-11}
}