Manganilvaite

CaFe2+Fe3+Mn2+(Si2O7)O(OH)
IMA status
  • Approved
IMA symbol
Mlv
IMA approved
2002
Also known as
  • IMA2002-016
  • Manganilvaiet

Where it forms, where it's found

Geological setting

In marble-hosted distal skarn-type orebodies.

Type locality
Osikovo deposit
  1. Septemvri Mine
  2. Madan Municipality
  3. Smolyan Province
  4. Bulgaria

41.4882°, 24.9104°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Streak
Black to brownish black
Tenacity
brittle
Cleavage
Distinct/Good

On (100)

Fracture
Irregular/Uneven
Density
3.92 g/cm³

Optical

Pleochroism
Visible

Bluish gray to grayish brown

Optical colour
Grayish blue to pale reddish brown
Anisotropism
Strong, grayish blue to pale reddish brown
Internal reflections
Red
Tropism
Anisotropic
Reflectance R%
(8.3,10.0) 400, (8.4,10.1) 420, (8.3,10.0) 440, (8.3,10.0) 460, (8.2,9.9) 480, (8.0,9.9) 500, (7.9,9.8) 520, (7.5,9.8) 540, (7.5,9.7) 546, (7.3,9.7) 560, (7.0,9.7) 580, (6.9,9.7) 589, (6.7,9.7) 600, (6.4,9.5) 620, (6.1,9.5) 640, (6.0,9.4) 650, (5.9,9.4) 660, (5.7,9.4) 680, (5.7,9.3) 700
Reflected-light panel
7.2 %anisotropic · dual curve
Specimen sRGB 97, 71, 40
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong, grayish blue to pale reddish brown
Reflected colour
Grayish blue to pale reddish brown
Internal reflections
Red

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 13.025 Å · b = 8.8514 Å · c = 5.8486 Å
Cell angles
β = 90.167 °
Ratio a:b:c
1 : 0.680 : 0.449
Unit cell volume
674.28 ų
Z
4
Morphology

Predominant forms: r(011), m(110), s(210) and o(111).

Type-locality form

Rarely well-shaped dipyramidal crystals, with a prismatic habit along c.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
35.30%
26FeIronIron255.845111.690
27.38%
14SiSiliconSilicon228.08556.170
13.77%
25MnManganeseManganese154.93854.938
13.47%
20CaCalciumCalcium140.07840.078
9.83%
1HHydrogenHydrogen11.0081.008
0.25%
Total407.875100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2002-016
  • Manganilvaiet

In other languages

German
IMA 2002-016 · Manganilvait
Italian
manganilvaite

Classification

Strunz
10th ed.

9.BE.07

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.07ManganilvaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2005Bonev, I. K., Vassileva, R. D., Zotov, N., Kouzmanov, K. (2005) Manganilvaite, CaFe2+Fe3+(Mn,Fe2+)(Si2O7)O(OH), a new mineral species of the ilvaite group, from Pb–Zn skarn deposits in the Rhodope Mountains, Bulgaria. The Canadian Mineralogist, 43 (3) 1027-1042 doi:10.2113/gscanmin.43.3.1027 DOI: 10.2113/gscanmin.43.3.1027
  2. 2005Zotov, N.; Kockelmann, W.; Jacobsen, S. D.; Mitov, I.; Paneva, D.; Vassileva, R. D.; Bonev, I. K. (2005) Structure and cation order in manganilvaite: a combined X-ray diffraction, neutron diffraction and Mössbauer study. The Canadian Mineralogist, 43 (3). 1043-1053 doi:10.2113/gscanmin.43.3.1043 DOI: 10.2113/gscanmin.43.3.1043
  3. 2015(2015) Manganilvaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Manganilvaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/manganilvaite-26363},
  note      = {Accessed 2026-05-11}
}