Keyite

(◻0.5Cu0.5)CuCdZn2(AsO4)3 · H2O
IMA status
  • Approved
IMA symbol
Key
IMA approved
1975
Also known as
  • IMA1975-002
  • Keyiet

Where it forms, where it's found

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Deep sky blue · blue
Streak
Pale blue
Cleavage
Distinct/Good

(001)

Density
5.106 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.8 – 1.87
Surface relief
Very high
Principal indices
nα 1.8 · nγ 1.87
Dispersion
r > v, strong
Extinction
Y = b; X ∧ c = 11°, variable with wavelength.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.654(3) Å · b = 12.780(5) Å · c = 6.840(3) Å
Cell angles
β = 99.11 °
Ratio a:b:c
1 : 1.097 : 0.587
Unit cell volume
1005.8 ų
Z
2
Morphology

Prismatic [001] to tabular (010), commonly tapering or showing sub-parallel stacking on (010). Dominant forms observed on SEM photos {010), (110), (210), (011), and perhaps (201).

Twinning

None observed.

Type-locality form

Small blue prisms in cavities in tennantite ore.

Comment

space group I2/a

Crystal structure

Synonyms

  • IMA1975-002
  • Keyiet

In other languages

German
IMA 1975-002 · Keyit
Italian
Keyite

Classification

Strunz
10th ed.

8.CA.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.50KeyiteSpecies
Dana
8th ed.

40.02.18

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.02AB2(XO4)2·xH2OType
  • 40.02.18— unnamed intermediate level —Group
  • 40.02.18KeyiteSpecies
CIM

20.3.22

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.22KeyiteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1977Fleischer, Michael, Cabri, Louis J., Pabst, and Adolf (1977) New mineral names. American Mineralogist, 62 (11-12) 1259-1262
  2. 1977Clark, Andrew M., Embrey, Peter G., Fejer, Eva E. (1977) Keyite: a New Mineral from Tsumeb. The Mineralogical Record, 8 (3) 87-90
  3. 1996Cooper, M.A., Hawthorne, F.C. (1996) The crystal structure of keyite, Cu2+3(Zn,Cu2+)4Cd2(AsO4)6(H2O)2, an oxysalt mineral with essential cadium. The Canadian Mineralogist: 34: 623-630.
  4. 1997Jambor, J.L., Roberts, A.C. (1997) New mineral names. American Mineralogist, 82, 207-210.
  5. 2005(2005) Keyite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Keyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/keyite-2191},
  note      = {Accessed 2026-05-11}
}