Khrenovite

Na3Fe3+2(AsO4)3
IMA status
  • Approved
IMA symbol
Khr
IMA approved
2018
Also known as
  • IMA2017-105
  • Khrenoviet

Where it forms, where it's found

Geological setting

Fumarole.

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Honey-coloured · red-brown · orange-brown · yellow-brown
Tenacity
brittle
Cleavage
None Observed

Optical

Optical type
Biaxial (+) · 2V measured = 80°
Refractive index
1.825 – 1.845
Surface relief
Very high
Principal indices
nα 1.825 · nβ 1.834 · nγ 1.845
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 12.2394(7) Å · b = 12.7967(5) Å · c = 6.6589(4) Å
Cell angles
β = 112.953(7) °
Ratio a:b:c
1 : 1.046 : 0.544
Z
4
Morphology

Coarse prismatic crystals and clusters.

Type-locality form

Coarse prismatic crystals up to 0.2 × 0.3 × 0.8 mm and clusters up to 1 mm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic374.922224.766
37.62%
8OOxygenOxygen1215.999191.988
32.14%
26FeIronIron255.845111.690
18.70%
11NaSodiumSodium322.99068.970
11.54%
Total597.414100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2017-105
  • Khrenoviet

In other languages

German
IMA 2017-105 · Khrenovit

Classification

Strunz
10th ed.

8.AC.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.05KhrenoviteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2022(2022) Khrenovite. Handbook of Mineralogy. Mineralogical Society of America
  2. 2022Pekov, Igor V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVIII. Khrenovite, Na3Fe3+2(AsO4)3, the member with the highest sodium in the alluaudite supergroup. Mineralogical Magazine, 86 (6) 897-902 doi:10.1180/mgm.2022.64DOI: 10.1180/mgm.2022.64
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Khrenovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/khrenovite-52882},
  note      = {Accessed 2026-05-11}
}