Olivenite

Cu2(AsO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Oli
Discovered
1786
Also known as
  • Acicular arseniate of copper
  • Arseniksaures Kupfererz
  • Cuivre Arseniaté (of Bournon)
  • +22 more

History

The name olivenite is, almost literally, olive ore — a small, sharp piece of German mineralogy that crossed into English in the nineteenth century. The mineral is a copper arsenate that crystallises in shades from grass-green to brownish-olive, and that colour is the whole story of how it came to be called what it is.

The earliest formal name was a chemist's label. In 1786 the German chemist Martin Klaproth described the species as arseniksaures kupfererzarsenic-acid copper ore — a description of its composition rather than its appearance. Three years later Abraham Gottlob Werner renamed it Olivenerz, alluding directly to the olive-green colour of the typical specimens. Other early labels followed: Holzkupfererzwood-copper ore — for the fibrous, wood-like variety, recorded by Bournon in 1801, and pharmacochalzite, proposed by Hausmann in 1813.

The modern English form arrived in 1820, when Robert Jameson exchanged the German suffix -erz for the Latinate -ite then becoming standard for mineral names. Olivenerz became olivenite, and the older labels gradually fell out of use.

The type locality — the place where the mineral was first identified — is Carharrack mine in the parish of Gwennap, in the copper country of Cornwall. Through the nineteenth century the species was found in some abundance in the upper workings of the St Day mines and near Redruth, associated with limonite — a soft, earthy iron oxide — and quartz.

Industrial & practical applications

Olivenite has no industrial role. The mineral is too scarce, too softly bonded, and too rich in arsenic for any commercial use as an ore — the copper it carries is more cheaply won from sulfide deposits, and the arsenate framework that gives it its olive colour makes it a hazard rather than a resource.

Its interest is mineralogical and scientific. Olivenite is the copper end-member of a substitution series with adamite, the zinc analogue Zn₂(AsO₄)(OH), in which copper and zinc replace one another freely in the same crystal structure. The intermediate term, zincolivenite, was approved as a distinct species by the International Mineralogical Association in 2006. Beyond that research interest, the mineral reaches the public mainly through collectors and mineral museums, where well-formed crystals from the classic Cornish workings and from oxidised copper-arsenic deposits elsewhere are prized for their colour and crystal habit.

Where it forms, where it's found

Geological setting

Oxidized zone of a copper deposit

Commonly found in the oxidized zone of arsenic-bearing copper deposits.

Type locality
Carharrack Mine
  1. Gwennap
  2. Cornwall
  3. England
  4. UK

50.2345°, -5.1741°

496recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Olive green to yellow or brown · gray-green · grayish white · light green in transmitted light.

Straw yellow if fibrous.

Streak
Olive green to brown
Tenacity
brittle
Cleavage
Poor/Indistinct

Indistinct on (101) and (110)

Fracture
Irregular/Uneven · Conchoidal
Density
4.46 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 80 – 90° · 2V calc = 46 – 84°
Refractive index
1.747 – 1.865
Surface relief
Very high
Principal indices
nα 1.747 – 1.780 · nβ 1.788 – 1.820 · nγ 1.829 – 1.865
Birefringence
0.084
Pleochroism
Weak

In green and yellow. Absorption Y > X, Z.

Dispersion
strong r > v or r < v moderate
Extinction
Y=c
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0840
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]840 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation840 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 8.5844(3) Å · b = 8.2084(3) Å · c = 5.9258(2) Å
Cell angles
β = 90.130(3) °
Ratio a:b:c
1 : 0.956 : 0.690
Unit cell volume
417.56 ų
Z
4
Morphology

Crystals elongated [100]; also short prismatic to acicular [001]; tabular on (011), (100), or (001), less common. Occurs as globular or reniform masses with a fibrous structure with the fibers straight and divergent, rarely irregular; curved lamellar; massive, granular to earthy; nodular.

Twinning

On (010)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
44.91%
8OOxygenOxygen515.99979.995
28.26%
33AsArsenicArsenic174.92274.922
26.47%
1HHydrogenHydrogen11.0081.008
0.36%
Total283.017100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • P

Synonyms

  • Acicular arseniate of copper
  • Arseniksaures Kupfererz
  • Cuivre Arseniaté (of Bournon)
  • Cuivre arseniaté en octaèdre aigus
  • Holzkupfererz
  • Laurochalcit
  • Laurochalcita
  • Laurochalcite
  • Olive Copper Ore
  • Olive-green Copper Ore
  • Olivenkupfer
  • Pharmacholzit
  • Pharmacholzite
  • Pharmacochalcit
  • Pharmacochalcite
  • Pharmacochalzit
  • Pharmacochalzite
  • Pharmacolzit
  • Pharmakochalcit
  • Pharmakochalcite
  • Pharmakochalzit
  • Prismatischer Olivenmalachit
  • Right Prismatic Arsenate of Copper
  • Wood-Arsenate
  • Wood-Copper

In other languages

French
Cu2AsO4(OH) · olivénite
German
Olivenit
Spanish
Olivenita
Italian
olivenite
Japanese
オリーブ銅鉱
Chinese
橄榄铜矿 · 橄欖銅礦
Russian
оливенит · оливинит

Classification

Strunz
10th ed.

8.BB.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.30OliveniteSpecies
Dana
8th ed.

41.06.06.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.06Olivenite GroupGroup
  • 41.06.06.01OliveniteSpecies
CIM

20.1.2

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.1Arsenates of CuGroup
  • 20.1.2OliveniteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. vol. 2, in two parts: 1025 (as Pharmacolzit).
  2. 1786Klaproth (1786) Schriften der Gesellschaft naturforschender Freunde in Berlin: 7: 160 (as Arseniksaures Kupfererz).
  3. 1789Werner (1789) Bergmaennusches Journal, Freiberg (Neues Bergmannische Journal): 382, 385 (as Olivenerz).
  4. 1794Richard Kirwan (1794) Elements of Mineralogy - second edition Vol. 1. P. Elmsly, The Strand.
  5. 1797Rashleigh, P. (1797) Specimens of British Minerals Selected from the Cabinet of Phillip Rashleigh. London. Part 1: pl. 11, figure 2; part 2 (1802): pl. 6 (as Olive-green Copper Ore).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Olivenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/olivenite-2981},
  note      = {Accessed 2026-05-11}
}