Alunogen

Al2(SO4)3(H2O)12 · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Alg
Also known as
  • Alunogenit
  • Alunogenita
  • Alunogenite
  • +23 more

Where it forms, where it's found

Geological setting

Forms by reaction of sulfates from decomposing sulfides with aluminous minerals in shales and slates; in gossan or altered wall rock of pyritic deposits in arid regions; in coal seams; in relatively low-temperature fumaroles.

271recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · silky in fibrous masses.
Transparency
Transparent
Colour
Colorless in crystals · aggregates white · or pale yellow or red from impurities.

colorless in transmitted light.

Streak
White
Cleavage

Perfect on (010) and probable on (100) and (313).

Density
1.732 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 31 – 69° · 2V calc = 46°
Refractive index
1.473 – 1.48
Surface relief
Low
Principal indices
nα 1.473 · nβ 1.474 · nγ 1.48
Dispersion
none
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.420(60) Å · b = 26.97(2) Å · c = 6.062(5) Å
Cell angles
α = 89.67(1) ° · β = 97.34(1) ° · γ = 91.53(1) °
Ratio a:b:c
1 : 3.635 : 0.817
Z
2
Morphology

Crystals rare, small; prismatic [001] or (010) with a hexagonal outline about [010]; very complex, with about 60 forms noted. Commonly as delicate fibrous masses or crusts; effloresences; massive, fibrous to 5 mm.

Twinning

On (010).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2915.999463.971
71.56%
16SSulfurSulfur332.06096.180
14.83%
13AlAluminiumAluminium226.98253.964
8.32%
1HHydrogenHydrogen341.00834.272
5.29%
Total648.387100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Alunogenit
  • Alunogenita
  • Alunogenite
  • Davit
  • Davita
  • Davite
  • Halotrichit (of Hausmann)
  • Halotrichite (of Hausmann)
  • Hydrotrisulfate d'alumine
  • Katharit
  • Katharita
  • Katharite
  • Katherit
  • Katherita
  • Katherite
  • Keramohalite (of Glocker)
  • Keramostypterit
  • Keramostypterita
  • Keramostypterite
  • Saldanite
  • Schwefelsaure Thonerde
  • Solfatarite
  • Stipterit
  • Stypterit
  • Stypterita
  • Stypterite

In other languages

French
Alunogène
German
Alunogen
Spanish
Alunógeno
Italian
alunogen · alunogeno
Russian
Алуноген

Classification

Strunz
10th ed.

7.CB.45

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.45AlunogenSpecies
Dana
8th ed.

29.08.06.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.08A2(XO4)3·H2OType
  • 29.08.06— unnamed intermediate level —Group
  • 29.08.06.01AlunogenSpecies
CIM

25.6.7

  • 25SulphatesClass
  • 25.6Sulphates of Al and TlGroup
  • 25.6.7AlunogenSpecies

Group, growth & confusion

Often grow together
8 minerals

Literature, links & citation

Citations
  1. 1824Beudant, François-Sulpice (1824) Traité élémentaire de minéralogie. (Première Edition)) [Elementary Treatise on Mineralogy. (First Edition)]. Chez Verdière.
  2. 1828Mill (1828) Quarterly Journal of Science, Literature, and Art, London: 25: 382. [as Davite]
  3. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  4. 1835Shepard C.U. (1835) Treatise on Mineralogy. First edition: vols. 2, 3: 188. [as Solfatarite]
  5. 1839Glocker, E.F. (1839) Handbuch der Mineralogie, 2nd. edition, Nürnberg: 689. [as Keramohalite]
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alunogen — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alunogen-162},
  note      = {Accessed 2026-05-11}
}