Diadochite

Fe3+2(PO4)(SO4)(OH) · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ddc
Discovered
1837
Also known as
  • Orthodiadochite
  • Phosphoreisensinter

Where it forms, where it's found

Geological setting

Slate altered by ground water, perhaps originally post-mine in occurrence.

Gossan deposits, coal deposits, late stage mineralization in granitic pegmatites, caves, post-mining deposition.

Type locality
Arnsbach
  1. Probstzella
  2. Saalfeld-Rudolstadt District
  3. Thuringia
  4. Germany

50.5808°, 11.3931°

78recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Yellow to greenish-yellow or brown · reddish brown · light green · light yellow · pale yellow to yellowish brown in transmitted light.
Streak
Yellow to yellow-brown
Tenacity
fragile
Cleavage
None Observed
Fracture
Conchoidal · Sub-Conchoidal
Density
2.0 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 55°
Refractive index
1.615 – 1.67
Surface relief
Moderate
Principal indices
nα 1.615 · nβ 1.618 – 1.638 · nγ 1.665 – 1.670 · n 1.60 – 1.61
Birefringence
0.06
Pleochroism
Non-pleochroic
Dispersion
r > v strong
UV response
Not fluorescent
Notes

Isotropic when glassy. Measured 2V = small.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.605

Crystallography

Crystal system
Amorphous
Morphology

Found as nodules or colloform crusts, massive; glassy, earthy.

Type-locality form

Kidney-shaped and stalactite-like shapes.

Comment

Amorphous to x-rays.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
56.10%
26FeIronIron255.845111.690
26.11%
16SSulfurSulfur132.06032.060
7.49%
15PPhosphorusPhosphorus130.97430.974
7.24%
1HHydrogenHydrogen131.00813.104
3.06%
Total427.813100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Orthodiadochite
  • Phosphoreisensinter

In other languages

French
diadochite
German
Diadochit
Spanish
Destinezita · Diadochita
Italian
Diadochite
Russian
диадохит

Classification

Strunz
10th ed.

8.DB.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.05DiadochiteSpecies
Dana
8th ed.

43.05.02.01

  • 43Compound Phosphates, Etc.Class
  • 43.05Hydrated Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.05.02— unnamed intermediate level —Group
  • 43.05.02.01DiadochiteSpecies
CIM

22.3.25

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.25DiadochiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1837Breithaupt, J.F.A. (1837) Bestimmung neuer mineralien. 2. Diadochit, Journal für Praktische Chemie, 10, 503-505. (as diadochit)
  2. 1873Feistmantel, K. (1873) Diadochit aus permischen Schichten in Böhmen. Lotos, Zeitschrift für Naturwissenschaften: 23: 33-36.
  3. 1875Rammelsberg, Carl Friedrich (1875) Handbuch der Mineralchemie (2nd ed.) Wilhelm Engelmann, Leipzig.
  4. 1880Carnot, A. (1880) Note sur deux variétés de diachochite (phospho-sulfate de fer) trouvées dans la mine d'anthracite de Paychagnard (Isère). Bulletin de la Société française de Minéralogie: 3: 39-42.
  5. 1885Cesàro, G. (1885) Etude chimique et cristallographique de la destinézite (diadochite de Visé). Annales de la Société géologique de Belgique: 12: 173-191.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Diadochite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/diadochite-1279},
  note      = {Accessed 2026-05-11}
}