Nickenichite

Na(Ca0.5Cu0.5)MgMg2(AsO4)3
IMA status
  • Approved
IMA symbol
Nkn
Discovered
1993
Also known as
  • IMA1992-014
  • Nickenichiet

Where it forms, where it's found

Geological setting

Scoriaceous basalt from a Quaternary volcano.

Type locality
Nickenichite-bearing fumarole
  1. Nickenicher Sattel
  2. Nickenich
  3. Pellenz
  4. Mayen-Koblenz
  5. Rhineland-Palatinate
  6. Germany
2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright blue to gray blue.
Tenacity
brittle
Cleavage
Perfect

(010) perfect; (100) and (101) good.

Density
4.06 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60 – 84° · 2V calc = 86°
Refractive index
1.714 – 1.783
Surface relief
High
Principal indices
nα 1.714 · nβ 1.744 · nγ 1.783
Birefringence
0.069
Pleochroism
Weak

Light blue to blue.

Dispersion
weak
Extinction
Z ∧ a = 28° on (010); Y = b.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0690
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]690 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation690 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 11.882 Å · b = 12.76 Å · c = 6.647 Å
Cell angles
β = 112.81 °
Ratio a:b:c
1 : 1.074 : 0.559
Z
4
Morphology

Fibrous to long prismatic. Elongate [101], commonly radial or lamellar parallel to (010), some showing (010), (100), and (101).

Type-locality form

Bright blue fibrous to long prismatic monoclinic grains up to 0.20 mm long and 0.03 mm in diameter, elongate [101], commonly radial or lamellar parallel to (010).

Comment

TMPM 48:153 (1993) structure.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic374.922224.766
39.82%
8OOxygenOxygen1215.999191.988
34.01%
12MgMagnesiumMagnesium324.30572.915
12.92%
29CuCopperCopper0.563.54631.773
5.63%
11NaSodiumSodium122.99022.990
4.07%
20CaCalciumCalcium0.540.07820.039
3.55%
Total564.471100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K
  • Mn
  • P

Synonyms

  • IMA1992-014
  • Nickenichiet

In other languages

German
IMA 1992-014 · Nickenichit
Italian
nickenichite

Classification

Strunz
10th ed.

8.AC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.10NickenichiteSpecies
Dana
8th ed.

38.02.03.09

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.03Alluaudite-Wyllieite Group (Alluaudite Subgroup)Group
  • 38.02.03.09NickenichiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1993Auernhammer, M., Effenberger, H., Hentschel, G., Reinecke, Th., Tillmanns, E. (1993) Nickenichite, a new arsenate from the Eifel, Germany. Mineralogy and Petrology, 48 (2) 153-166 doi:10.1007/bf01163094DOI: 10.1007/bf01163094
  2. 1994Jambor, John L., Roberts, Andrew C., Puziewicz, Jacek (1994) New Mineral Names. American Mineralogist, 79 (5-6) 570-574
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 2007(2007) Nickenichite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2019Hatert, Frédéric (2019) A new nomenclature scheme for the alluaudite supergroup. European Journal of Mineralogy, 31 (4) 807-822 doi:10.1127/ejm/2019/0031-2874DOI: 10.1127/ejm/2019/0031-2874
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nickenichite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nickenichite-2900},
  note      = {Accessed 2026-05-11}
}