Petedunnite

CaZnSi2O6
IMA status
  • Approved
IMA symbol
Pdu
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-073

Where it forms, where it's found

Geological setting

metamorphosed stratiform zinc deposit

Type locality
Buckwheat pit
  1. Franklin Mine
  2. Franklin
  3. Sussex County
  4. New Jersey
  5. USA

41.1147°, -74.5872°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark green
Streak
greenish white
Cleavage
Distinct/Good

(110)

Density
3.68 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70 – 90° · 2V calc = 88°
Refractive index
1.68 – 1.7
Surface relief
High
Principal indices
nα 1.68 · nβ 1.69 · nγ 1.70
Pleochroism
Visible

X = Y = light yellow; Z = light green.

Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 9.82(2) Å · b = 9.00(1) Å · c = 5.27(2) Å
Cell angles
β = 105.6(2) °
Ratio a:b:c
1 : 0.916 : 0.537
Z
4
Type-locality form

portions of an anhedral crystal consisting of a mosaic of 10-100 μm-sized subgrains containing abundant inclusions.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
37.26%
30ZnZincZinc165.38065.380
25.38%
14SiSiliconSilicon228.08556.170
21.80%
20CaCalciumCalcium140.07840.078
15.56%
Total257.622100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Na

Synonyms

  • IMA1983-073

In other languages

French
Petedunnite
German
IMA 1983-073 · Petedunnit
Italian
Petedunnite

Classification

Strunz
10th ed.

9.DA.15

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DAInosilicates with 2-periodic single chains, Si2O6; pyroxene familyGroup
  • 9.DA.15PetedunniteSpecies
Dana
8th ed.

65.01.3a.05

  • 65Inosilicates Single-width, Unbranched Chains, (w=1)Class
  • 65.01Single-Width Unbranched Chains, W=1 with chains P=2Type
  • 65.01.3a— unnamed intermediate level —Group
  • 65.01.3a.05PetedunniteSpecies
CIM

14.7.15

  • 14Silicates not Containing AluminumClass
  • 14.7Silicates of Ba, Sr and ZnGroup
  • 14.7.15PetedunniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1987Essene, Eric J., Peacor, Donald R. (1987) Petedunnite (CaZnSi2O6), a new zinc clinopyroxene from Franklin, New Jersey, and phase equilibria for zincian pyroxenes. American Mineralogist, 72 (1-2) 157-166
  2. 1997Fehr, K.T., Hobelsberger, B. (1997) Experimentelle Bestimmung der chemischen Potentiale von Hedenbergit in der Mischreihe Hedenbergit-Petedunnit. Beiheft zum European Journal of Mineralogy: 9: 98.
  3. 1998Rothkopf, A.L., Fehr, K.T. (1998) The chemical potential of hedenbergite in hedenbergite-peetedunnite solid solution determined by EMF measurements. Terra Abstracts: 10: Supplement 1: 53.
  4. 2004Huber, A. L.; Heuer, M.; Fehr, K. T.; Bente, K.; Schmidbauer, E.; Bromiley, G. D. (2004) Characterization of synthetic hedenbergite (CaFeSi2O6)-petedunnite (CaZnSi2O6) solid solution series by X-ray powder diffraction and 57Fe Mössbauer spectroscopy. Physics and Chemistry of Minerals, 31 (2). 67-79 doi:10.1007/s00269-003-0335-1DOI: 10.1007/s00269-003-0335-1
  5. 2012Huber, A. L.; Heuss-Assbichler, S.; Fehr, K. T.; Bromiley, G. D. (2012) Petedunnite (CaZnSi2O6): Stability and phase relations in the system CaO-ZnO-SiO2. American Mineralogist, 97 (4). 739-749 doi:10.2138/am.2012.3836DOI: 10.2138/am.2012.3836
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Petedunnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/petedunnite-3173},
  note      = {Accessed 2026-05-11}
}