Arseniosiderite

Ca2Fe3+3O2(AsO4)3 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Assd
Discovered
1842
Also known as
  • Arseniansiderit
  • Arseniansiderita
  • Arseniansiderite
  • +7 more

Where it forms, where it's found

Geological setting

An uncommon secondary mineral formed by the oxidation of earlier arsenic-bearing phases.

Oxidized zones of arsenic-bearing deposits.

Type locality
Manganese deposit
  1. Romanèche-Thorens
  2. La Chapelle-de-Guinchay
  3. Mâcon
  4. Saône-et-Loire
  5. Bourgogne-Franche-Comté
  6. France

46.1889°, 4.7336°

211recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Sub-metallic · silky.
Transparency
Opaque
Colour
Golden-yellow to yellow-brown · reddish-brown · brown · black

Reddish brown to brownish yellow in transmitted light.

Streak
Ocher-yellow.
Tenacity
brittle
Cleavage
Perfect

On (001), perfect.

Fracture
Fibrous
Density
3.58 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.792 – 1.898
Surface relief
Very high
Principal indices
nα 1.792 – 1.815 · nβ 1.87 – 1.898 · nγ 1.87 – 1.898
Birefringence
0.08
Pleochroism
Strong

X = Nearly colourless to pale brownish or brownish red Y = Z = Brownish red to dark brownish red

Dispersion
r > v
Extinction
X perpendicular to {100}
Luminescence
None
UV response
Not fluorescent
Notes

Pseudouniaxial (-). 2V (measured) = small, essentially 0.

Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 17.76 Å · b = 19.53 Å · c = 11.3 Å
Cell angles
β = 96 °
Ratio a:b:c
1 : 1.100 : 0.636
Z
12
Morphology

Pseudotetragonal. Cell space group: A2/a. Commonly occurs as flattened fibers, in radial aggregates, and felted to granular masses. Euhedral crystals rare.

Comment

A2/a

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
36.24%
33AsArsenicArsenic374.922224.766
29.95%
26FeIronIron355.845167.535
22.32%
20CaCalciumCalcium240.07880.156
10.68%
1HHydrogenHydrogen61.0086.048
0.81%
Total750.488100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arseniansiderit
  • Arseniansiderita
  • Arseniansiderite
  • Arseniosideriet
  • Arseniosideritt
  • Arsenocrocit
  • Arsenocrocita
  • Arsenocrocite
  • Arsenokrokit
  • Mazapilite

In other languages

German
Arseniosiderit
Spanish
Arseniosiderita
Italian
Arseniosiderite

Classification

Strunz
10th ed.

8.DH.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.30ArseniosideriteSpecies
Dana
8th ed.

42.08.04.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.04Mitridatite GroupGroup
  • 42.08.04.03ArseniosideriteSpecies
CIM

20.9.11

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.11ArseniosideriteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1842Dufrénoy, A. (1842) Description de l´arsénio-sidérite, nouvelle espèce d'arséniate de fer. Annales des mines: 2: 343-348.
  2. 1843Dufrénoy, A. (1843) Description de l'arsénio-sidérite, nouvelle espèce d'arséniate de fer. Comptes rendus de l’Académie des sciences de Paris: 16: 22.
  3. 1846Rammelsberg, C. (1846) Mineralanalysen. Annalen der Physik, Halle, Leipzig: 68: 505-518 (508).
  4. 1847Glocker, Ernst Friedrich (1847) Generum et specierum mineralium, secundum ordines naturales digestorum synopsis, omnium, quotquot adhuc reperta sunt, mineralium nomina complectens [A synopsis of the genera and species of minerals, according to their natural orders, including the names of all the minerals that have yet been discovered.]. Eduardus Anton. 348 pp.
  5. 1873Church, A. H. (1873) New analyses of certain mineral arseniates and phosphates. Journal of the Chemical Society, 26. 101-111 doi:10.1039/js8732600101DOI: 10.1039/js8732600101
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arseniosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arseniosiderite-360},
  note      = {Accessed 2026-05-11}
}