Pigeonite

(Mg,Fe,Ca)2Si2O6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pgt
Discovered
1900
Also known as
  • Calc-clinobronzite
  • Calc-clinoenstatite
  • Calc-clinohypersthene

Where it forms, where it's found

Type locality
Pigeon Point
  1. Cook County
  2. Minnesota
  3. USA

47.9981°, -89.5381°

293recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Black · brown · greenish brown
Streak
greyish white
Cleavage
Distinct/Good

Optical

Optical type
Biaxial (+) · 2V measured = 32° · 2V calc = 26°
Refractive index
1.683 – 1.752
Surface relief
High
Principal indices
nα 1.683 – 1.722 · nβ 1.684 – 1.722 · nγ 1.704 – 1.752
Dispersion
weak to distinct
Michel-Lévy diagramhighlighted lineδ = 0.0255
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]255 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation255 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P1 21/c 1
Cell parameters
a = 9.7 Å · b = 8.95 Å · c = 5.24 Å
Cell angles
β = 108.59 °
Ratio a:b:c
1 : 0.923 : 0.540
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
28.45%
8OOxygenOxygen615.99995.994
24.45%
20CaCalciumCalcium240.07880.156
20.41%
14SiSiliconSilicon228.08556.170
14.31%
12MgMagnesiumMagnesium224.30548.610
12.38%
Total392.620100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Mn
  • Na
  • K
  • H2O

Synonyms

  • Calc-clinobronzite
  • Calc-clinoenstatite
  • Calc-clinohypersthene

In other languages

French
Pigeonite
German
Pigeonit
Spanish
Pigeonita
Italian
Pigeonite
Japanese
ピジョン輝石
Chinese
易变辉石 · 易變輝石
Simplified Chinese
易变辉石

Classification

Strunz
10th ed.

9.DA.10

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DAInosilicates with 2-periodic single chains, Si2O6; pyroxene familyGroup
  • 9.DA.10PigeoniteSpecies
Dana
8th ed.

65.01.01.04

  • 65Inosilicates Single-width, Unbranched Chains, (w=1)Class
  • 65.01Single-Width Unbranched Chains, W=1 with chains P=2Type
  • 65.01.01P2/c clinopyroxenesGroup
  • 65.01.01.04PigeoniteSpecies
CIM

14.23.1

  • 14Silicates not Containing AluminumClass
  • 14.23Silicates of Fe, Mg, CaGroup
  • 14.23.1PigeoniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1900Winchell, A.N. (1900) Mineralogical and petrographic study of the gabbroid rocks of Minnesota, and more particularly, of the plagioclasytes. The American Geologist: 26(4): 197–245.
  2. 1909Dana, Edward S., Ford, William E. (1909) A System of Mineralogy - Second Appendix to the Sixth Edition of Dana's System of Mineralogy. John Wiley & Sons.
  3. 1953Kuno, H., Hess, H. H. (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes. American Journal of Science, 251 (10) 741-752 doi:10.2475/ajs.251.10.741DOI: 10.2475/ajs.251.10.741
  4. 1960Morimoto, Nobuo, Appleman, Daniel E., Evans., Howard T. (1960) The crystal structures of clinoenstatite and pigeonite. Zeitschrift für Kristallographie, 114 (1). 120-147 doi:10.1524/zkri.1960.114.1-6.120 DOI: 10.1524/zkri.1960.114.1-6.120
  5. 1969Morimoto, Nobuo, Tokonami, Masayasu (1969) Oriented exsolution of augite in pigeonite. American Mineralogist, 54 (7-8) 1101-1117
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pigeonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pigeonite-3210},
  note      = {Accessed 2026-05-11}
}