Xanthoconite

Ag3AsS3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Xcn
Discovered
1840
Also known as
  • Rittingerit
  • Rittingerite
  • Xanthocone
  • +1 more

Where it forms, where it's found

Geological setting

Hydrothermal veins

Type locality
Himmelsfürst Mine
  1. Brand-Erbisdorf
  2. Mittelsachsen
  3. Saxony
  4. Germany

50.8572°, 13.2953°

84recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Translucent
Colour
Red-orange · yellow-orange · red-brown · brown
Streak
Orange-yellow
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (001)

Fracture
Sub-Conchoidal
Density
5.54 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 34°
Dispersion
r < v strong
Extinction
X ≃ c, Y ≃ a, Z = b
Tropism
Anisotropic
Reflectance R%
(33.7,37.1) 400, (32.2,36.1) 420, (30.7,35.1) 440, (29.1,33.7) 460, (27.6,32.1) 480, (26.1,30.1) 500, (24.8,28.5) 520, (23.7,27.3) 540, (22.7,26.3) 560, (22.0,25.5) 580, (21.5,24.8) 600, (21.3,24.4) 620, (21.0,24.1) 640, (20.8,23.8) 660, (20.6,23.6) 680, (20.4,23.5) 700
Notes

Refractive indices = ~3.

Reflected-light panel
24.9 %anisotropic · dual curve
Specimen sRGB 168, 123, 79
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 11.99 Å · b = 6.26 Å · c = 17.08 Å
Cell angles
β = 110 °
Ratio a:b:c
1 : 0.522 : 1.425
Z
8
Morphology

Tabular, laths, pyramids

Twinning

(001) pseudoorthorhombic twins

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver3107.868323.604
65.41%
16SSulfurSulfur332.06096.180
19.44%
33AsArsenicArsenic174.92274.922
15.15%
Total494.706100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Rittingerit
  • Rittingerite
  • Xanthocone
  • Xanthokonit

In other languages

French
15122-59-5 · Ag3AsS3 · Xanthoconite
German
Rittingerit · Xanthokon · Xanthokonit
Spanish
Xantoconita
Italian
Xanthoconite · xantoconite

Classification

Strunz
10th ed.

2.GA.10

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GANeso-sulfarsenites, etc. without additional SGroup
  • 2.GA.10XanthoconiteSpecies
Dana
8th ed.

03.04.02.01

  • 03SulfosaltsClass
  • 03.04ø = 3Type
  • 03.04.02Xanthoconite Group (Ruby Silver)Group
  • 03.04.02.01XanthoconiteSpecies
CIM

5.2.4

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.4XanthoconiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
5 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1840Breithaupt, A. (1840), Xanthokon, ein neues Glied der Ordnung der Blenden. Journal für Praktische Chemie: 20: 67-69.
  2. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  3. 1950(1950): Mineralogical Magazine 35: 72.
  4. 1950Peacock, M. A. (1950) Studies of mineral sulpho-salts: XV. Xanthoconite and pyrostilpnite. Mineralogical Magazine and Journal of the Mineralogical Society, 29 (211) 346-358 doi:10.1180/minmag.1950.029.211.11 DOI: 10.1180/minmag.1950.029.211.11
  5. 1968Engel, P., Nowacki, W. (1968) Die Kristallstruktur von Xanthokon, Ag3AsS3. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 24 (1) 77-81 doi:10.1107/s056774086800172xDOI: 10.1107/s056774086800172x
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Xanthoconite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/xanthoconite-4330},
  note      = {Accessed 2026-05-11}
}