Segnitite

PbFe3+3(AsO4)(AsO3OH)(OH)6
IMA status
  • Approved
IMA symbol
Sgt
Discovered
1991
IMA approved
1991
Also known as
  • IMA1991-017
  • Segnitiet
  • Sulfatfreier Beudantit

Where it forms, where it's found

Geological setting

Oxidation of primary ore rich in galena and arsenopyrite-loellingite.

Rare mineral found in the oxidation zone of hydrothermal ore deposits.

Type locality
Kintore opencut
  1. Broken Hill South Mine (BHS Mine
  2. South Mine)
  3. Broken Hill
  4. Broken Hill district
  5. Yancowinna Co.
  6. New South Wales
  7. Australia

-31.9707°, 141.4604°

174recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Greenish to yellowish-brown
Streak
Pale yellow
Tenacity
brittle
Cleavage
Distinct/Good

Good on (0001)

Fracture
Irregular/Uneven
Density
4.2 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.955 – 1.975
Surface relief
Very high
Principal indices
nω 1.975 · nε 1.955
Pleochroism
Weak

Pale to medium yellow.

UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 7.359(3) Å · c = 17.113(8) Å
Z
3
Morphology

Rhombohedral (mainly acute rhombohedra), pseudo-octahedral, pseudo-cubic or tabular crystals; very rarely also acicular. The principal forms present in the type material are (112) and (001).

Twinning

None observed

Type-locality form

Greenish brown to yellowish brown, pseudo-octahedral crystals up to 1 mm across, and as aggregates, crusts and clusters of yellowish brown rhombohedral crystals up to 5 mm high.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
29.64%
82PbLeadLead1207.200207.200
27.42%
26FeIronIron355.845167.535
22.17%
33AsArsenicArsenic274.922149.844
19.83%
1HHydrogenHydrogen71.0087.056
0.94%
Total755.621100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1991-017
  • Segnitiet
  • Sulfatfreier Beudantit

In other languages

German
IMA 1991-017 · Segnitit
Spanish
Segnitita
Italian
Segnitite

Classification

Strunz
10th ed.

8.BL.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BLWith medium-sized and large cations, (OH, etc.):RO4 = 3:1Group
  • 8.BL.10SegnititeSpecies
Dana
8th ed.

42.07.04.04

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.07(AB)2(XO4)Zq·xH2OType
  • 42.07.04Arsenocrandallite GroupGroup
  • 42.07.04.04SegnititeSpecies
CIM

20.5.13

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.5Arsenates of Ti and PbGroup
  • 20.5.13SegnititeSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1992Birch, W. D., Pring, A., Gatehouse, B. M. (1992) Segnitite, PbFe3H(AsO4)2(OH)6, a new mineral in the lusungite group from Broken Hill, New South Wales, Australia. American Mineralogist, 77 (5-6) 656-659
  2. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  3. 2005(2005) Segnitite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2009Sejkora, J., Škovíra, J., Čejka, J., Plášil, J. (2009) Cu-rich members of the beudantite-segnitite series from the Krupka ore district, the Krušné hory Mountains, Czech Republic. Journal of GEOsciences, 54 (4) 355-371
  5. 2013Petrov, P.M., Pekov, I.V. (2013) Segnitite from Kremikovtsi Mine – a New Mineral for Bulgaria, 197-205. Sofia Initiative Preservation of Mineral Diversity.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Segnitite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/segnitite-3606},
  note      = {Accessed 2026-05-11}
}